The kinetics and equilibrium of the decomposition of hydrogen iodide have been studied extensively:2HI(g) ⇆ H₂(g) + I₂(g)
What is kinetics?The area of classical mechanics known as kinetics studies how forces and torques affect the motion of mass-containing objects. The traditional mechanics of moving bodies is referred to by authors using the term kinetics as well as the nearly identical name dynamics (q.v.). In contrast, statics deals with bodies at rest and in an equilibrium state. Kinematics and kinetics are both included under dynamics (the description of motion in terms of position, velocity, and acceleration, apart from the influence of forces, torques, and masses).
The division of classical mechanics into kinematics and dynamics by authors who do not use the term kinetics includes statics as a specific instance of dynamics when the sum of the forces and the sum of the torques are both zero.
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What is the answer:
C4H8+H2=
Explain the difference between potential energy and kinetic energy.
Sentence Starters
"Potential Energy is. . "
"Kinetic Energy is. . "
"The difference between potential energy and kinetic energy is. . ."
Answer:
Potential energy is the stored energy in an object or thing, while kinetic energy is the energy which an object contains because of a particular motion.
Explanation:
Potential energy is energy that is stored for example a wind up toy, it has energy but in order for you to get kinetic energy, it has to move. So kinetic energy is moving energy.
The difference is that potential is stored and kinetic is moving energy.
Calculate the change of enthalpy for the reaction 2Al (s) + 3Cl2 (g) --> 2AlCl3 (s) from the following reactions
Reaction 1: 2Al (s) + 6HCl (aq) --> 2AlCl3 (aq) + 3H2 (g) Change in enthalpy: -1049 kJ
Reaction 2: HCl (g) --> HCl (aq) Change in enthalpy: -74.8 kJ/mol
Reaction 3: H2 (g) + Cl2 (g) --> 2HCl (g) Change in enthalpy: -1845. kJ/mol
Reaction 4: AlCl3 (s) --> AlCl3 (aq) Change in enthalpy: -323. kJ/mol
Include the following:
The numerical answer with correct units.
State which reactions, if any, you had to "Flip".
State which reactions you had to multiply, if any, to get the correct amount of the compound. Also, include how much you multiplied the reaction by.
The change of enthalpy for the given reaction is equal to -6387 KJ.
What is the enthalpy change?Enthalpy can be defined as the sum of internal energy and the product of volume and Pressure, expressed as shown below:
H = U + PV
The change in enthalpy between the beginning and final states can be expressed as:
ΔH = ΔU + ΔPV
Given reactions with enthalpy change are shown below:
2Al (s) + 6HCl (aq) → 2AlCl₃ (aq) + 3H₂ (g) }×1 ΔH₁ = -1049 kJ
HCl (g) → HCl (aq) } ×6 ΔH₂ = -74.8 kJ/mol
H₂ (g) + Cl₂ (g) → 2HCl (g) }× 3 ΔH₃ = -1845. kJ/mol
AlCl₃ (aq) → AlCl₃ (s) }× 2 ΔH₄ = +323. kJ/mol
\(\triangle H^o_f =1\times \triangle H_1 +6\times \triangle H_2+3\times \triangle H_3+2\times \triangle H_4\)
\(\triangle H^o_f =1\times (-1049) +6\times (-74.8)+3\times (-1845)+2\times (+323)\)
\(\triangle H^o_f =-6387 KJ\)
Therefore, the change of enthalpy for the reaction of the formation of aluminum chloride is -6387 KJ.
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2. In the space provided, describe the common characteristics of inner planets and outer planets.
Answer: The four inner planets have shorter orbits, slower spin, no rings, and they are made of rock and metal. The four outer planets have longer orbits and spins, a composition of gases and liquids, numerous moons, and rings
Explanation:
pls mark as brainlist by the way we are in the same school :)
The atomic mass of iron is 55.85, and oxygen is 16.0. What is the mass of 6.02 × 1023 molecules of Fe2O3?
Answer:159.7grams
Explanation:
(55.85)2+(16)3
159.7grams
Answer:
The correct answer for plato/edmentum is C (159.7g)
a medical laboratory catalog describes the pressure in a cylinder of a gas as 14.82 mpa. what is the pressure of this gas in atmospheres and torr?
Ideal gas law is valid only for ideal gas not for vanderwaal gas. Therefore, the pressure in atm and torr is 148.2 atm and 1,12,632 torr respectively.
What is ideal gas equation?Ideal gas equation is the mathematical expression that relates pressure volume and temperature. There is no force of attraction between the particles.
pressure= 14.82 mpa
= 14.82 × 10⁶ pa
1 atm = 10⁵ pa
1 Pa = 1/10⁵ atm
pressure= 14.82 × 10⁶× 1/10⁵ atm
= 148.2 atm
1 atm = 760 torr
pressure= 148.2 ×760 torr
= 1,12,632 torr
Therefore, the pressure in atm and torr is 148.2 atm and 1,12,632 torr respectively.
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PLSS HELP! The gas carbon dioxide is a pure substance. Which of the following is true about carbon dioxide? (4 points)
a. Carbon and oxygen are chemically bonded in it.
b. Carbon and oxygen retain their original identity in it.
c. It can be separated into carbon and oxygen using physical methods.
d. The proportion of carbon and oxygen is different in different samples of the gas.
Answer:
A. Carbon and oxygen are chemically bonded in it.
Explanation:
I saw someone with the exact question and they said A so yea ♥
At STP, iodine, I2, is a crystal, and fluorine, F2, is a gas. Iodine is soluble in ethanol, forming a tincture of iodine. A typical tincture of iodine is 2% iodine by mass.
66 Compare the strength of the intermolecular forces in a sample of I2 at STP to the strength of the intermolecular forces in a sample of F2 at STP
At STP (Standard Temperature and Pressure), iodine is present in a crystalline form, whereas fluorine is in a gaseous form. Iodine is also soluble in ethanol and produces a tincture of iodine. Typically, a 2% iodine mass is present in a tincture of iodine.
The strength of the intermolecular forces in I2 (iodine) at STP is significantly higher than the strength of the intermolecular forces in F2 (fluorine) at STP. This is because of the difference in the bonding type, which is the primary factor that affects the strength of the intermolecular forces. Iodine is bonded covalently in its crystalline form, with every I2 molecule sharing electrons with another I2 molecule, making it a very strong intermolecular force. This bond is also known as a covalent bond. On the other hand, fluorine is bound by weak van der Waals forces due to its gaseous form, which are primarily dipole-dipole interactions. Since they are less polar, the van der Waals forces in F2 are weaker than in I2. These intermolecular forces are weaker because fluorine is in a gaseous form, while iodine is in a crystalline form. Hence, the strength of the intermolecular forces in I2 is much greater than the strength of the intermolecular forces in F2.For such more question on intermolecular
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At STP, iodine (I2) is a solid crystal and fluorine (F2) is a gas. A sample of I2 at STP is held together by van der Waals forces, which are weaker intermolecular forces. On the other hand, a sample of F2 at STP is held together by much stronger intermolecular forces than I2 due to its smaller size.
Therefore, F2 has stronger intermolecular forces than I2. It can be explained in a long answer as follows:At standard temperature and pressure, iodine (I2) is a solid crystalline substance. Its physical state is a solid because the intermolecular forces that bind the iodine molecules together are weak van der Waals forces. These forces are much weaker than chemical bonds, and they hold molecules in a condensed phase like a liquid or a solid. The forces of attraction between the iodine atoms in I2 are much weaker than the forces of attraction between the fluorine atoms in F2.
As a result, the boiling point of I2 is much lower than the boiling point of F2. F2 is a gas at STP since it is held together by much stronger intermolecular forces than I2 due to its smaller size. Fluorine has an electron density that is spread out over a larger area than iodine, making it more polarizable. The larger polarizability leads to stronger instantaneous dipoles and, as a result, stronger London dispersion forces. Since intermolecular forces are responsible for determining the physical state of a substance, F2 is a gas, whereas I2 is a solid. As a result, F2 has stronger intermolecular forces than I2.
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HURRY NEED ANSER NOW!!!
A machine makes work easier by____
A. Multiplying the force exerted
B. Maintaining the distance over which the force is exerted
C. Adding the forces exerted
D. Dividing the force exerted
Answer:
your answer would be C.
Explanation:
Machines make work easier by increasing the amount of force that is applied, increasing the distance over which the force is applied, or changing the direction in which the force is applied. sorry if im wrong.
Which of the following elements has 2 electrons in the 4s sublevel?
Answer:
B. Ca
Explanation:
Let's look at the electron configurations of all four elements (I am going to write it in noble gas configuration to make it simpler):
Mg electron configuration: [Ne]3s2
Ca electron configuration: [Ar]4s2
Ar electron configuration: [Ar]
K electron configuration: [Ar] 4s1
We notice that Ca has two electrons in the 4s sublevel, which satisfies what the question is asking for.
The answer is thus B. Ca.
an atom has 19 protons and 20 neutrons. what is the atomic number with steps
Answer:
39
Explanation:
add em up
in the distillation of a pure material, why does all of the pure material no vaportize once the boiling point is reched.
In the distillation of a pure material, all of the pure material not vaporize once the boiling point is reached because more heat would need to be added to the distillate in order to vaporize the liquid from its boiling point.
During distillation, the process of vaporizing a liquid and collecting the resulting vapor as a purified substance, it is important to consider the energy requirements involved.
When a liquid reaches its boiling point, it undergoes a phase change from the liquid phase to the gas phase. This phase change requires the input of energy in the form of heat. The heat breaks the intermolecular forces holding the liquid molecules together, allowing them to transition into the gas phase.
The heat required to vaporize a liquid is not solely determined by the boiling point. The heat required to convert a liquid into a gas is known as the heat of vaporization, and it varies depending on the substance.
When distilling a liquid, such as water, the heat of vaporization must be supplied to convert the liquid into vapor. This energy is absorbed by the liquid, and it is essential to provide continuous heating to maintain the distillation process.
As the liquid is heated and reaches its boiling point, vaporization begins. However, the rate at which the liquid vaporizes depends on the amount of heat being supplied. If the heat input is insufficient, the vaporization process will be slower, and not all of the liquid will vaporize at once.
To ensure the complete vaporization of a liquid during distillation, a sufficient amount of heat must be continuously applied to the system. This allows the heat of vaporization to be continually supplied to the liquid, facilitating the conversion of the entire liquid into vapor.
If the heat input is insufficient, the vaporization process will be slower, and the liquid may not vaporize all at once. Providing adequate and continuous heating is crucial to ensure the complete conversion of the liquid into vapor during distillation.
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what is molecular formula of Ozone?
Answer:
the molecular formula of Ozone is O_3.
Answer: O₃
Explanation:
The chemical formula of ozone is O3. In the earth's stratosphere, ozone is formed from a two-step reactive process. First, sunlight breaks apart an oxygen molecule (O2 you'll recall) into two oxygen atoms. In the second step, these oxygen atoms collide with another oxygen atom to make ozone.
Which identifies an oxidation-reduction reaction?
a double replacement reaction
a neutralization reaction
a reaction in which oxidation numbers change
a reaction in which no electrons are transferred
The statement that identifies an oxidation-reduction reaction is a reaction in which oxidation numbers change (option C).
What is a redox reaction?A redox or oxidation-reduction reaction is a chemical reaction in which some of the atoms have their oxidation number changed.
In a chemical reaction that involves oxidation and reduction, the oxidation number of the involved ions either decreases or increases.
Therefore, the statement that identifies an oxidation-reduction reaction is a reaction in which oxidation numbers change.
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LINKS WILL BE REPORTED PLEASE HELP
Certain bacteria live and grow on the roots of some plants and produce chemicals that are beneficial to the plants. Which of the following observations best supports the claim that this relationship is beneficial to the plants?
A.When the bacteria are removed from the plant roots and are grown in a laboratory setting, they fail to survive
B.The population size of the bacteria varies greatly depending on the chemistry of the soil and the type of the plant
C.Plants with a higher density of the bacteria on their roots have increased rates of survival and reproduction
D.The chemical produced by the bacteria can be created by humans and added to the soil where it reaches the roots of the plant
C. the denser the plants the better.
Answer:
C
Answer: Plants with higher density of the bacteria on their roots have increased rates of survival reproduction
Explanation:
What might be the biggest obstacle to getting cooperation for a clean up of the river
The biggest obstacle to getting cooperation for a clean up of the river is the lack of awareness among the public about the negative impacts of the pollutants and waste on the environment and public health.
A river cleanup project aims at eliminating pollutants and waste that harm the ecosystem and water quality, however, if the public is not aware of the negative impact of these pollutants on the environment, they may not view the project as a priority. Hence, the first and most significant step towards securing public cooperation is to raise awareness about the importance of a clean and healthy environment. Environmental groups, schools, and local government officials can take up the responsibility of informing the public about the risks associated with water pollution, the negative impacts on health, aquatic life, and the overall ecosystem. To promote engagement and participation, officials can organize environmental campaigns, rallies, and workshops to mobilize the public to participate in the cleanup efforts. Overall, awareness and education can play a vital role in mobilizing the public to participate in cleanup efforts to preserve and protect the environment.
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a mixture of gaseous reactants is put into a cylinder, where a chemical reaction turns them into gaseous products. the cylinder has a piston that moves in or out, as necessary, to keep a constant pressure on the mixture of . the cylinder is also submerged in a large insulated water bath. (see sketch at right.) the temperature of the water bath is monitored, and it is determined from this data that of heat flows into the system during the reaction. the position of the piston is also monitored, and it is determined from this data that the system does of work on the piston during the reaction. is the reaction exothermic or endothermic? exothermic endothermic does the temperature of the water bath go up or down? up down neither does the piston move in or out? in out neither does the reaction absorb or release energy? absorb release neither
The reaction is exothermic and therefore the temperature of the water bath go up.
What is exothermic reaction?A chemical reaction involves the movement of energy to or from the environment.
An exothermic reaction occurs when energy is transmitted to the environment, increasing temperature.
The reaction is exothermic because energy is released as a result of it.The released heat will be employed to operate on the piston and to raise the temperature due to the heat input from the eater bath, respectively.As a result, the bath's temperature will increase.
As was already indicated, the heat generated will exert force on the piston, causing it to move out.Energy produced during the reaction. Heat will therefore go from the gas combination to the bath.The solution is hence "out."
We know the released energy = work + heat supplied to the bath
energy = 390 kJwork = 117 kJClearly,
heat = energy - work
= (390 - 117) kJ
= 273 kJ
Thus, when the energy is absorbed by the system, a positive sign is assigned.
Therefore, the reaction absorb energy.
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22. How many atoms are there in 344.75 g of gold nugget? a. 1.05 x 10 to the power of 24 atoms b. 1.05 x 10 to the power of 23 atoms c. 6.02 x 10 to the power of 23 atoms d. 197 atoms Is B the answer
Answer:
1.053×10²⁴ atoms of gold
Explanation:
Hello,
Gold nugget are usually the natural occurring gold and they contain 85% - 90% weight of pure gold.
In this question, we're required to find the number of atoms in 344.75g of a gold nugget.
We can use mole concept relationship between Avogadro's number and molar mass.
1 mole = molar mass
Molar mass of gold = 197 g/mol
1 mole = Avogadro's number = 6.022 × 10²³ atoms
Number of mole = mass / molar mass
Mass = number of mole × molar mass
Mass = 1 × 197
Mass = 197g
197g is present in 6.022×10²³ atoms
344.75g will contain x atoms
x = (344.75 × 6.022×10²³) / 197
X = 1.053×10²⁴ atoms
Therefore 344.75g of gold nugget will contain 1.053×10²⁴ atoms of gold
As per the atoms the 344.5 g of gold nuggets have a 1.05x10 and have a power of 24 atoms.
Gold nugget are usually the natural occurring gold and they contain 85% - 90% weight of pure gold. In this question, we're required to find the number of atoms in 344.75g of a gold nugget. 1.053×10²⁴ atoms of gold.Learn more about the atoms are there.
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When chlorine gas is bubbled into an aqueous solution of potassium iodide, the colourless solution turns brown.
i) Write an ionic equation for the reaction that takes place
ii) What is the name given to this type of reaction?
iii) Why does the solution turn brown?
Answer:
When chlorine (Cl 2 ) gas is passed through an aqueous solution of potassium iodide (KI), the products formed are solid iodine (I2) and potassium chloride (KCl). This is a displacement reaction in which the less reactive iodine in potassium iodide is displaced by the more reactive chlorine. The equation can be written as:
2KI(aq)+Cl2(g)→2KCl(aq)+I2 (s)
TRUE / FALSE. consist of alternating layers of marine and non-marine rocks.
The given statement "Consist of alternating layers of marine rocks and non-marine rocks" will be false. Because, the deposition of sedimentary rocks is influenced by various factors such as geological processes, sediment sources, and depositional environments.
The presence of alternating layers of marine and non-marine rocks depends on the specific geological history and depositional conditions of a particular region.
Sedimentary rocks can be formed in marine environments (such as oceans, seas, and estuaries) or non-marine environments (such as lakes, rivers, deserts, and glaciers). The type of sediment and the characteristics of the depositional environment determine the composition of the sedimentary rocks formed.
In some cases, sedimentary sequences may exhibit alternating layers of marine and non-marine rocks. This can occur, for example, in regions where sea levels fluctuated over time, leading to periods of marine deposition followed by periods of non-marine deposition as the shoreline shifted. This pattern can result in the development of transgressive-regressive sequences, which show alternating marine and non-marine layers.
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An insoluble solid that forms from a chemical reaction is called
Precipitates are insoluble ionic solid products of a reaction, formed when certain cations and anions combine in an aqueous solution. The determining factors of the formation of a precipitate can vary.
Can I Plz Have help?!?!?!?
(Q1) What is the correct value for coefficient (A)?
A. 1
B. 2
C. 3
D. 4
(Q2) What is the correct value for coefficient (B)?
A. 1
B. 2
C. 3
D. 4
(Q3) What is the correct value for coefficient (C)?
A. 1
B. 2
C. 3
D. 4
(Q4)What is the correct value for coefficient (D)?
A. 1
B. 2
C. 3
D. 4
(Q5) If there is enough energy and H2, then how many moles of Sn02 will react with 2 moles of H2 and produce 1 mole of Sn and 2 moles of H2O? How many moles of SnO2 does this balanced equation represent?
A. 0.5
B. 1.0
C. 1.5
D. 2.5
(Q6)The reactants in this equation are _________.
A. SnO2 and Sn
B. Sn and H2O
C. SnO2 and H2
D. H2 and H2O
(Q7)The products in this equation are _________.
A. SnO2 and Sn
B. Sn and H2O
C. SnO2 and H2
D. H2 and H2O
(Q8)This reaction is ___________.
A. endothermic
B. exothermic
Answer:
1. A
2. B
3. A
4. B
5. B
6.C
7. B
8. A
Explanation:
SnO₂ + H₂ + energy → Sn + H₂0
The reaction is between Tin(iv) oxide and hydrogen gas to form tin and water molecules.
Notice the reaction is not balance therefore let us balance the equation. To balance the equation the number of atoms on both side (reactant and product)of the equation must be equal.
SnO₂ +2H₂ → Sn + 2H₂0
The equation is balanced . SnO₂ has coefficient of 1 , H₂ has coefficient of 2, Sn has coefficient of 1 and H₂0 has coefficient of 2.
Q5
SnO₂ + 2H₂→ Sn + 2H₂0
1 moles of SnO₂ will balance the equation
Q6
The reactant is on the left side of the chemical equation. Therefore the reactants are Tin(iv) oxide and hydrogen molecules (SnO₂ and H₂)
Q7
The product is on the right side of the chemical equations .Therefore, the products are Tin and water molecules(Sn and H₂0).
Q8
The reaction is an endothermic reaction because it absorb heat from it environment.
What is the [H+] if the pH of a
solution is 3.20?
Which ocean borders Africa on the western coast?
pls answer for 20 coiins
Answer:
indian ocean
Explanation:
In today’s lab, Mr. Gray asked students to weigh out 1.5 moles of CaCO3 to use for their experiment. However, the scale only shows the amount in grams. How many grams of Calcium Carbonate are in 1.5 moles?
Considering the definition of molar mass, the mass of 1.5 moles of CaCO₃ is 150 grams.
Definition of molar massThe molar mass of substance is a property defined as its mass per unit quantity of substance, in other words, molar mass is the amount of mass that a substance contains in one mole.
The molar mass of a compound (also called Mass or Molecular Weight) is the sum of the molar mass of the elements that form it (whose value is found in the periodic table) multiplied by the number of times they appear in the compound.
Molar mass of CaCO₃In this case, you know the molar mass of the elements is:
Ca= 40 g/moleC= 12 g/moleO= 16 g/moleSo, the molar mass of the compound CaCO₃ is calculated as:
CaCO₃= 40 g/mole + 12 g/mole + 3× 16 g/mole
Solving:
CaCO₃= 100 g/mole
Mass of 1.5 mol CaCO₃Next, you can apply the following rule of three: If by definition of molar mass 1 mole of the compound contains 100 grams, 1.5 moles of the compound contains how much mass?
\(mass=\frac{1.5 molesx100 grams}{1 mole}\)
mass= 150 grams
Finally, the mass of 1.5 moles of CaCO₃ is 150 grams.
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a heliox deep-sea diving mixture contains 2.0 g of oxygen to every 98.0 g of helium. what is the partial pressure of oxygen when this mixture is delivered at a total pressure of 7.7 atm?
The partial pressure of oxygen in the heliox deep-sea diving mixture is 0.0193 atm.
To calculate the partial pressure of oxygen in the heliox deep-sea diving mixture, we need to use the mole fraction of oxygen and the total pressure of the mixture.
First, we need to determine the number of moles of each gas in the mixture:
Moles of oxygen = 2.0 g / 32.00 g/mol = 0.0625 mol
Moles of helium = 98.0 g / 4.00 g/mol = 24.50 mol
Next, we can calculate the mole fraction of oxygen:
Mole fraction of oxygen = moles of oxygen / total moles = 0.0625 mol / (0.0625 mol + 24.50 mol) = 0.0025
We can then use the mole fraction of oxygen and the total pressure of the mixture to calculate the partial pressure of oxygen:
Partial pressure of oxygen = mole fraction of oxygen x total pressure = 0.0025 x 7.7 atm = 0.0193 atm
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In the electrowinning process, a Metallurgical/Chemical Engineer uses an Infrared (IR) camera to detect metallurgical short-circuits (hot spots) over the anodes and cathodes. Given that the mass of an electron is 9. 109× 1031 and Rydberg’s constant is 1. 090×107 −1 , determine the energy (in MJ) applied when 5 mol of IR photons having a wavelength of 32 nm is used in the copper electrolysis process
In the electrowinning process, the energy applied using 5 mol of IR photons with a wavelength of 32 nm is 1.863 MJ.
1. Convert wavelength to energy using the equation: E = (hc)/λ, where h is Planck's constant (6.626×10⁻³⁴ Js), c is the speed of light (3×10⁸ m/s), and λ is the wavelength (32 nm = 32×10⁻⁹ m).
2. Calculate the energy of one IR photon: E = (6.626×10⁻³⁴ Js × 3×10⁸ m/s) / (32×10⁻⁹ m) = 6.184×10⁻¹⁹ J.
3. Determine the energy for 5 moles of IR photons: Total energy = 6.184×10⁻¹⁹ J × 5 × 6.022×10²³ photons/mol = 1.863×10⁶ J.
4. Convert energy to megajoules: 1.863×10⁶ J = 1.863 MJ.
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explain the degree of migration of each component on the column. explain the order in which each component elute from the column taking into consideration (in no particular order):
The separation of different molecules in a mixture using column chromatography, which is a widely used separation technique in various fields of science, including chemistry and biology.
The degree of migration of each component on the column depends on the molecule's physical properties, such as molecular weight and polarity, as well as the nature of the column and the exclusion limits of the resin used. In general, lighter molecules with lower molecular weights and higher polarity tend to migrate more quickly through the column and elute earlier, while heavier and less polar molecules migrate more slowly and elute later. The nature of the column, including its packing material and the presence of charged functional groups, also influences the degree of migration and elution order of each component. Finally, the exclusion limits of the resin used determine the size range of molecules that can be separated by the column, with larger molecules being excluded and eluting later than smaller ones. Overall, a combination of these factors determines the degree of migration and elution order of each component in a column separation.
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QUESTION: Explain the degree of migration of each component on the column. Explain the order in which each component elute from the column taking into consideration (in no particular order): i. The molecule's physical properties (molecular weight) ii. The nature of the column (how the column works) iii. Exclusion limits of the resin used. The exclusion limits of a resin indicate the range of molecular weights of the molecules it can separate.
what information about an atom is communicated in an electron configuration
Answer: Electron configurations describe where electrons are located around the nucleus of an atom.
Explanation: For example, the electron configuration of lithium, 1s²2s¹, tells us that lithium has two electrons in the 1s subshell and one electron in the 2s subshell
Help me please will give brainliest
well excuse the "s" at the end