In the given chemical reaction, H2S is being oxidized to sulfur and NO3− is being reduced to NO gas.
The given balanced chemical equation is:3 H2S (aq) + 2 H (aq) + 2 NO3−(aq) → 3 S(s) + 2 NO(g) + 4 H2O (ℓ)Oxidation is the process in which a chemical species loses electrons in a chemical reaction. Reduction is the process in which a chemical species gains electrons in a chemical reaction.Here, H2S undergoes oxidation and NO3− undergoes reduction. So, H2S is being oxidized to sulfur and NO3− is being reduced to NO gas. The reducing agent in the reaction is H2S while the oxidizing agent is NO3−.
The oxidation and reduction half-reactions can be written as follows:Oxidation half-reaction:H2S → S + 2 H+ + 2 e-Reduction half-reaction:NO3- + 4 H+ + 3 e- → NO + 2 H2OBy adding the two half-reactions, we get the overall equation as shown below:3 H2S (aq) + 2 H+ (aq) + 2 NO3−(aq) → 3 S(s) + 2 NO(g) + 4 H2O (ℓ).
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Which statement accurately describes binary star systems?
They have more than two stars.
They have stars that are always visible.
They include large groups of stars.
They have stars that might appear to wobble.
Answer:
The correct answer is D.They have stars that may appear to wobble.
Explanation:
Binary star - Wikipediaen.wikipedia.org › wiki › Binary_star
''Astronomers have discovered some stars that seemingly orbit around an empty space. Astrometric binaries are relatively nearby stars which can be seen to wobble around a point in space, with no visible companion. The same mathematics used for ordinary binaries can be applied to infer the mass of the missing companion''
-Wikipediaen.wikipedia.org › wiki › Binary_star
-Edge 2021
might be a lil late but YW
The statement that accurately describes binary star systems is: "They have stars that might appear to wobble."
What is the binary star system?Binary star systems are systems that consist of two stars that orbit around their common center of mass.
The gravitational interaction between the two stars causes them to orbit around each other, and their motion can cause them to appear to wobble as seen from Earth. This wobbling can be detected by astronomers and used to determine the properties of the stars, such as their masses and distances from Earth.
Here in the question,
Binary star systems consist of two stars, not more than two stars, so the statement "They have more than two stars" is incorrect.
Binary star systems do not necessarily have stars that are always visible. The visibility of stars depends on their location and the observer's position on Earth, so the statement "They have stars that are always visible" is incorrect.
Binary star systems are not large groups of stars, but rather consist of two stars in orbit around each other, so the statement "They include large groups of stars" is incorrect.
Therefore, The statement "They have stars that might appear to wobble." is correct.
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what is the valence configuration of potassium
Answer:
Explanation:
Ground state electron configuration of potassium (K) is 1s2 2s2 2p6 3s2 3p6 4s1. The valency of the element is determined by electron configuration in the excited state. This electron configuration shows that the last shell of the potassium atom has an unpaired electron (4s1). So the valency of potassium is 1.
I’m second guessing myself here...
Fill in the blank
Potential energy is energy an object has due to its ____
or condition
Answer :position
Explanation:
Potential energy is the energy stored in an object due to its position
Ian drinks two and seven eighths liters of water. Farida drinks one and two eighths liters of water. How many more liters of water does Ian drink than Farida
150 more liters of water does Ian drink than Farida.
briefly:-Ian drinks = 278 liters
Farida drinks = 128 liters
Ian drink than Farida = 278-128 =150 liters .
Why does life depend on water?We only have a three to five day survival time without fluids because approximately 60% of our body is made up of water .Addition to cleaning out waste and controlling body temperature, transporting nutrients, and being essential for digestion, water serves many other crucial tasks in the body.
small molecule of water. There are three hydrogen atoms and one oxygen atom in it. Hydrogen bonding, a force, is responsible for the adhesion of water molecules. Water is capable of incredible feats because of it.
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Answer: 1 5/8
Explanation:
Y-ray photons with a wavelength of 2.45×10-5 nm.
Express the energy numerically in kilojoules per mole.
PLEASE help me
Y-ray photons with a wavelength of 2.45×10-5 nm. energy of photon is 8.11 × 10⁻¹²J.
given data is as follows :
wavelength = 2.45 × 10⁻⁵ nm
energy of photon is given by the following formula , we get :
E = hf
where E = energy of photon
h = Planck constant = 6.63 × 10⁻³⁴ j.s
f = frequency
and frequency = c / λ
the formula will be:
E = h c / λ
c = speed of light = 3 × 10⁸ m/s
E = (6.63 × 10⁻³⁴ × 3 × 10⁸ ) / 2.45 × 10⁻⁵ × 10⁻⁹
E = 8.11 × 10⁻¹²J
Thus, Y-ray photons with a wavelength of 2.45×10-5 nm. energy of photon is 8.11 × 10⁻¹²J.
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How can you find the number of protons from the nuclide symbol?
It is the difference in the mass number and atomic number.
It is half the number in the upper left (half the mass number).
It is the number in the lower left (atomic number).
It is the number in the upper left (atomic number).
It is the number in the upper left (mass number).
Answer: It is the number in the upper left (atomic number).
Explanation: The atomic number is normally the number of protons. I hope this helps.
Is sugar more or less dense than water
Answer:
Objects with a higher density than the substance it is submerged in will sink. Objects with a lesser density than the substance it is submerged in will float. Sugar substitute is less dense than water and sugar or high fructose corn syrup is denser than water.
Explanation:
The oxide of which of the following metals should have the greatest lattice energy?
A.) calcium
B.) strontium
C.) magnesium
D.) beryllium
E.) barium
The oxide of the metal with the highest charge and smallest ionic radius is expected to have the greatest lattice energy.
Among the given options, the metal with the highest charge is beryllium (Be2+), which has a charge of +2. Beryllium also has a small ionic radius, meaning its ions are closely packed together. As a result, the oxide of beryllium (BeO) is likely to have the greatest lattice energy. Lattice energy is a measure of the energy released when gaseous ions come together to form a solid lattice structure. It is influenced by the magnitude of the charges on the ions and the distances between them. Higher charges and smaller ionic radii result in stronger attractions between ions, leading to higher lattice energy.
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aluminum is produced by the electrolytic reduction of alumina the anode in the reaction is graphite which is oxidized to co2 what mass of graphite must be consumed in order to produce 1000 kg of aluminum
The production of aluminum by the electrolytic reduction of alumina involves the oxidation of graphite at the anode, which produces carbon dioxide (CO2) gas. In order to calculate the mass of graphite that must be consumed to produce 1000 kg of aluminum, we need to use the stoichiometry of the reaction.
The balanced chemical equation for the reaction is:
2 Al2O3 + 3 C → 4 Al + 3 CO2
This equation tells us that for every 3 moles of graphite (C) consumed, we can produce 4 moles of aluminum (Al). We can use this information to calculate the amount of graphite required to produce a given amount of aluminum.To start, we need to determine the number of moles of aluminum in 1000 kg of the metal. The molar mass of aluminum is 26.98 g/mol, so:
1000 kg Al × (1000 g/kg) ÷ (26.98 g/mol) = 37,051.5 mol A
Next, we can use the stoichiometry of the reaction to determine the number of moles of graphite required to produce this amount of aluminum. For every 4 moles of Al produced, we need 3 moles of C:
37,051.5 mol Al × (3 mol C/4 mol Al) = 27,788.6 mol C
Finally, we can convert the number of moles of graphite to mass, using the molar mass of carbon (12.01 g/mol):
27,788.6 mol C × 12.01 g/mol = 333,391 g or 333.4 kg
Therefore, approximately 333.4 kg of graphite must be consumed in order to produce 1000 kg of aluminum by the electrolytic reduction of alumina.
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calculate the speed of a train that is traveling west distances of 100 miles in 2 hours
a. 200m/h
b. 200m/h west
c. 50m/h
d. 50 m/h west
Answer:
d
Explanation:
The train will travel for 2 hours to travel a distance of 100 miles with a speed of 50m/h. Therefore, option (C) is correct.
What is the speed?The speed of a body is defined as the rate of change in the position of a body w.r.t. time.
Speed is a scalar parameter with both magnitude and no direction. A simple mathematical formula common way to determine speed.
S = d / t
where S is the speed, d is the distance moved by a body and t is the time.
Although the SI unit for speed is the same as velocity is m/s and can also be expressed in miles per hour (mph), and kilometers per hour (kph).
Given, the distance traveled by train, d = 100 miles
The time taken by train = 2 hrs
The speed of the train = distance/ time = 100/2 = 50m/h
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Does Anyone Need Answer to Your Question
Analyze the graph to describe the solubility of barium nitrate,Ba(NO₃)₂.
At 60°C, ✔ 200 g must be added to 1 L of
water to make a saturated solution.
At 25°C, the solubility is about ✔ 100 g per liter.
A solution that contains 600 g Ba(NO₃)₂. in
3 L of H2O at 70°C is ✔ unsaturated.
For a solution that contains 300 g Ba(NO₃)₂ in 3 L of H₂O at 60°C to become saturated, ✔ 300 g
solute must be added.
Yes, the solubility information provided in the graph can be summarized as follows:
1. At 60°C, a saturated solution of barium nitrate (Ba(NO₃)₂) requires 200 g to be added to 1 L of water. This means that at this temperature, the maximum amount of Ba(NO₃)₂ that can dissolve in 1 L of water is 200 g.2. At 25°C, the solubility of Ba(NO₃)₂ is approximately 100 g per liter. This indicates that at this lower temperature, a smaller amount of Ba(NO₃)₂ can dissolve in 1 L of water compared to the solubility at 60°C.3. A solution that contains 600 g of Ba(NO₃)₂ in 3 L of water at 70°C is classified as unsaturated. This means that the amount of Ba(NO₃)₂ in the solution is below the maximum solubility at that temperature.4. For a solution that contains 300 g of Ba(NO₃)₂ in 3 L of water at 60°C to become saturated, an additional 300 g of the solute must be added. This implies that the current solution is not saturated, as it has not reached the maximum solubility at that temperature.In summary, the solubility of barium nitrate (Ba(NO₃)₂) increases with temperature, with higher temperatures allowing for more solute to dissolve in the solvent (water).
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what is the correct terms for atom with a full valence shell?
Answer:
octet rule
Explanation:
What is the notation for the enthalpy of solution?
O -Hsol
O AH sol
Ο ΔΕ
O +Hsol
The notation for the enthalpy of the solution is ∆Hsol. The correct answer is option ∆Hsol.
The enthalpy of solution is a measure of the amount of heat absorbed or released when a solute is dissolved in a solvent to form a solution. If the value of ∆Hsol is positive, it means that heat is absorbed during the process of dissolving the solute, while a negative value of ∆Hsol indicates that heat is released during the same process. This value is often used to predict whether a given solute will dissolve in a given solvent, as well as the relative amounts of solute and solvent that will be required to form a solution. The enthalpy of solution can be calculated experimentally by measuring the temperature change that occurs when a known amount of solute is dissolved in a known amount of solvent. Alternatively, it can be calculated theoretically using thermodynamic data for the solute and solvent.For more questions on enthalpy
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Which electron are the valence electrons of the atom?
A. The electrons that have lost their charge
B. The electrons closest to the nucleus
C. The electrons that have entered the nucleus
D. The electrons farthest away from the nucleus
Answer:
D.
Explanation:
The valence electrons are located in the outermost shell.
In theory, a plant kept in total darkness could still manufacture glucose, if it were supplied with which molecules? Explain_ plant can survive with NADPH, CO2,and ATP Differentiate between Cz and C4 plants, list plant examples of each and explain how climate change might influence the distribution of Cz and C plants in North America.
C3 plants' leaves don't have Kranz anatomy. During cellular respiration, electrons that have lost their energy are transferred to the an inorganic molecule. Here, photosynthesis takes place after the stomata.
What produce do plants make from glucose?Plants use glucose as a source of energy and to create other compounds like starch and cellulose. Cell walls are constructed using cellulose. As a food source, starch is kept in seeds or other plant parts.
What substances do plants employ to create glucose?During photosynthesis, plants take up water (H2O) or co2 (CO2) from environment and the soil. In the plant cell, carbon dioxide is reduced, meaning means it gets electrons, whereas water is oxidised, meaning means it loses electrons. As a result, carbon dioxide is transformed into glucose and water into oxygen.
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Lana drew the diagram below to model asexual reproduction. Based on Lana's diagram, which statement explains the results of asexual reproduction? A. The offspring are not genetically identical to the parent, because each offspring receives only half of the chromosomes from a single parent. B. The offspring are not genetically identical to the parents, because two parents each contribute half of their chromosomes to each offspring. C. The offspring are genetically identical to the parent, because each offspring receives a complete copy of a single parent's chromosomes. D. The offspring are genetically identical to the parents, because two parents each contribute a complete copy of their chromosomes to each offspring.
Based on Lana's diagram, the correct statement that explains the results of asexual reproduction is C. The offspring are genetically identical to the parent, because each offspring receives a complete copy of a single parent's chromosomes.
What happens in asexual reproduction?In the diagram, the parent cell divides into two identical daughter cells, each of which contains a complete copy of the parent cell's genetic material.
This type of reproduction, where a single parent produces offspring that are genetically identical to itself, is called asexual reproduction. It is the process by which many unicellular organisms, such as bacteria and some protists, reproduce.
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A gas mixture contains 1.52 atm of Ne, 766 mmHg of He and Ar. What is the partial pressure, in atmospheres, of At if the gas mixture has a total pressure of 3.27atm
Answer:
0.74 atm.
Explanation:
From the question given above, the following data were obtained:
Pressure of Ne (Pₙₑ) = 1.52 atm
Pressure of He (Pₕₑ) = 766 mmHg
Total pressure (Pₜ) = 3.27 atm
Pressure of Ar (Pₐᵣ) =?
Next, we shall convert the pressure of He from mmHg to atm. This can be obtained as follow:
760 mmHg = 1 atm
Therefore,
766 mmHg = 766 mmHg × 1 atm / 760 mmHg
766 mmHg = 1.01 atm
Finally, we shall determine the partial pressure of Ar. This can be obtained as follow:
Pressure of Ne (Pₙₑ) = 1.52 atm
Pressure of He (Pₕₑ) = 1.01 atm
Total pressure (Pₜ) = 3.27 atm
Pressure of Ar (Pₐᵣ) =?
Pₜ = Pₙₑ + Pₕₑ + Pₐᵣ
3.27 = 1.52 + 1.01 + Pₐᵣ
3.27 = 2.53 + Pₐᵣ
Collect like terms
3.27 – 2.53 = Pₐᵣ
Pₐᵣ = 0.74 atm
Thus the partial pressure of Ar is 0.74 atm.
How many water molecules (H2O) can be produced from 6 molecules of hydrogen gas (white) reacting with 6 molecules of oxygen gas (red)
The number of water molecules (H₂O) can be produced from 6 molecules of hydrogen gas (white) reacting with 6 molecules of oxygen gas (red) is 6 molecules.
The balanced chemical equation for the reaction between hydrogen and oxygen to form water is:
2H₂ + O₂ → 2H₂O
From this equation, we can see that 2 molecules of hydrogen (H₂) react with 1 molecule of oxygen (O₂) to form 2 molecules of water (H₂O).
Therefore, if we have 6 molecules of hydrogen gas and 6 molecules of oxygen gas, we can use stoichiometry to determine how many molecules of water will be produced.
6 molecules of H₂ = 6 x 2 = 12 hydrogen atoms
6 molecules of O₂ = 6 x 2 = 12 oxygen atoms
Since the ratio of hydrogen to oxygen in the reaction is 2:1, we have enough oxygen atoms to react with only 6 of the hydrogen atoms. This means that 6 molecules of water will be produced.
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what do we call the organized steps taken to answer a scientific problem?
a. Observation
b. Conclusion
c. Experiment
d. Data Analysis
Conclusion call the organized steps taken to answer a scientific problem.
What is Scientific method?The Scientific Method is defined as a logical and rational order of steps through which scientists come to conclusions related to the world around them. The Scientific Method helps in the organization of thoughts and procedures by which the scientists are in confident in the answers they find.
What is observation?OBSERVATION is considered as the first step through which they get to know how they want to go about your research.
What is hypothesis?HYPOTHESIS is the step in which we think hypothetical means about the answer which we have to find.
What is prediction?PREDICTION is our specific belief about our scientific idea:like, If my hypothesis is true, then I predict we will discover this.
What is Experiment?EXPERIMENT is defined as the tool that we invent to answer our question.
What is conclusion?CONCLUSION is the answer which our experiment gives.
Thus, we concluded that the Conclusion call the organized steps taken to answer a scientific problem.
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Fumaric acid and malonic acid are both diprotic acids. a. Sketch the general shape of the curve for a diprotic acid with Ka1 >> Ka2. Explain how to determine pKa1, pKa2, and the molecular weight. b. Sketch the general shape of the curve for a diprotic acid with Ka1 ≈ Ka2. c. Sketch the general shape of a curve for a triprotic acid with Ka1 >> Ka2 >> Ka3.
The general shape of a diprotic acid with Ka1 >> Ka2 is a steep decline followed by a gradual decline, while a diprotic acid with Ka1 ≈ Ka2 shows a gradual decline followed by a steeper decline. In the case of a triprotic acid with Ka1 >> Ka2 >> Ka3, the curve consists of three gradual declines representing each neutralization step.
What are the general shapes of the curves for diprotic and triprotic acids with different equilibrium constants?In a. The general shape of the curve for a diprotic acid with Ka1 >> Ka2 is a steep decline followed by a gradual decline. To determine pKa1, titrate the acid with a strong base, and pKa1 is the pH at the midpoint of the first equivalence point.
To determine pKa2, titrate the acid with a strong base after fully neutralizing the first proton, and pKa2 is the pH at the midpoint of the second equivalence point. The molecular weight can be determined by mass spectrometry or by summing the atomic masses of the constituent elements.
In b. The general shape of the curve for a diprotic acid with Ka1 ≈ Ka2 is a gradual decline followed by a steeper decline. The two equivalence points are closer together compared to the case of Ka1 >> Ka2.
In c. The general shape of the curve for a triprotic acid with Ka1 >> Ka2 >> Ka3 is a series of three gradual declines. Each equivalence point represents the neutralization of one proton, and the pKa values can be determined at the midpoints of the corresponding equivalence points.
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You wish to know the enthalpy change for the formation of liquid from PCl3 from the elements.
P4(s) + 6 Cl2(g) ? 4 PCl3(l) ?rH° = ?
The enthalpy change for the formation of PCl5 from the elements can be determined experimentally, as can the enthalpy for the reaction of PCl3(l) with more chlorine to give PCl5(s):
P4(s) + 10 Cl2(g) ? 4 PCl5(s) ?rH° = -1774.0 kJ/mol-rxn
PCl3(l) + Cl2(g) ? PCl5(s) ?rH° = -123.8 kJ/mol-rxn
Use these data to calculate the enthalpy change for the formation of 1.00 mol of PCl3(l) from phosphorous and chlorine.
-2269.2kJ is the enthalpy change of a given equation for 4 moles . the negative value indicates that the given reactions are spontaneous reactions .
These equations and enthalpy of reaction is given by Hess’s law, the chemical equation can be treated as algebraic expressions . That means the enthalpy change of the overall reaction is the sum of the enthalpy changes of the intermediate reactions.
P4(s) + 10 Cl2(g)--> 4 PCl5(s) ΔH°rxn= -1774.0 kJ
PCl3(l) + Cl2(g)--> PCl5(s) ΔH°rxn = -123.8 kJ ( Multiply by 4 )
then the value of enthalpy change for equation 2 be -495.2kJ
then according to enthalpy change equation
delta H = delta h1 - delta h2
delta H = -1774.0 -(- 495.2)
delta H = - 2269.2KJ
for 4 moles the value of enthalpy change is -2269.2kJ
the value of enthalpy change for 1 mole is - 567.3 KJ
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Balance the folowing equation.
S + 02
ws
SO:
Answer:
s+o2=so2
Explanation:
i hope it will help u
What is mean by SI unit ?Mention any five physical quantities with their SI units.
Answer:
SI, The International System of Units is a scientific method of expressing the magnitudes or quantities.
amount of substance (mole)time (second)length (metre)mass (kilogram)electric current (ampere)Hope this helps!
one thousand grams of water (about 1 l) contains 55.5 moles of water molecules. (one mole is 6.022 x 1023 particles). one electron is removed from every hundredth water molecule and placed in a container 100. m from the water. a. how many water molecules are there in the water container?
The number of water molecules in the container when one electron is removed from every hundredth water molecule and placed in a container is 100. m from the water is 3.30 x 1025.
Given,1 liter of water = 1000 g of water1 mole of water molecules = 6.022 x 1023 particles.
Therefore, 55.5 moles of water molecules = 55.5 x 6.022 x 1023 particles = 3.33 x 1025 particles one electron is removed from every hundredth water molecule.
So, 1 electron is removed from 1% of water molecules. Therefore, the number of water molecules from which the electron is removed = (1/100) x 3.33 x 1025 = 3.33 x 1023 molecules.
Now, this electron is placed 100 m away from the water container. The distance between the water container and the electron is not relevant for finding the number of water molecules in the container, hence can be ignored.
So, the number of water molecules in the container = Total number of water molecules - number of water molecules from which electron is removed= 3.33 x 1025 - 3.33 x 1023 = 3.30 x 1025.
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What is the mass of 3.25 miles of AsF5
Answer:
169.913616 g/mol
Explanation: This is weight of AsF5 molecular weight
Is xenon and potassium a covalent ionic bond? Or is it neither
Xenon and potassium do not form a bond. Xenon is a noble gas, and as such, it is chemically unreactive and does not form chemical bonds with other elements under normal conditions. Potassium, on the other hand, is an alkali metal and forms ionic bonds with other elements.
Xenon and potassium are two different elements that do not form a chemical bond. Xenon is a noble gas and is chemically unreactive, meaning it does not form chemical bonds with other elements. Noble gases are characterized by their full valence shell of electrons, which makes them stable and resistant to chemical reactions. Potassium, on the other hand, is an alkali metal and is highly reactive, meaning it readily forms ionic bonds with other elements. Ionic bonds are formed between positive and negative ions and are held together by electrostatic forces. Since xenon and potassium do not form a bond, it would not be classified as a covalent or ionic bond. The concept of covalent and ionic bonds only applies to chemical bonds between atoms.
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how many significant figures are in the number 0.00208?
The number 0.00208 has three significant figures. Significant figures are the digits in a number that carry meaningful information about its precision. In the case of 0.00208, the digits 2, 0, and 8 are all significant.
Zeros that appear before the first nonzero digit (leading zeros) are not considered significant. Therefore, the leading zero in 0.00208 is not counted as a significant figure.
To summarize, the number 0.00208 has three significant figures: 2, 0, and 8.
If we write the number as 0.002080, the trailing zero after the 8 would be considered significant, indicating that there are four significant figures in the number.
If we express the number in scientific notation, such as 2.08 x 10^(-3), the digits 2, 0, and 8 remain significant, regardless of the exponent. Hence, there are still three significant figures in the number.
It's important to note that significant figures are not limited to decimal numbers. They are also relevant in whole numbers and in calculations involving measurements with uncertainties.
Understanding the concept of significant figures allows us to maintain consistency and precision in calculations and measurements. By recognizing the significant figures in a number, we can appropriately determine the number of decimal places to retain in the result of a calculation or measurement.
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A student conducts an experiment to determine how the temperature of water affects the time for sugar to dissolve. In each trial, the student uses a different amount of water and a different temperature of water. What is wrong with this experimental design? The student did not change enough independent variables. The student changed more than one independent variable. The student does not have a dependent variable. The student needs to perform more trials.
According to the question, the student set out to study the influence of temperature of water on the time for sugar to dissolve but a different amount of water and a different temperature of water was used in each trial. This experiment is wrong because the student changed more than one independent variable.
The aim of the student in the experiment was to determine the influence of temperature of water on the time for sugar to dissolve.
This experiment should have one independent variable (temperature) and one dependent variable (time for sugar to dissolve).
However, the student also changed the amount of water used at each trial meaning that another independent variable has been introduced. This makes it difficult for us to arrive at reliable conclusions from the experiment.
The amount of water ought to have been held constant throughout the experiment.
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Calculate the standard cell potential at 25 degrees C for the following cell reaction from standard free energies of formation (Appendix C).
2Al(s) + 3Cu
2
+
(aq) →
2Al
3
+
(aq) + 3Cu(s)
The standard cell potential at 25 degrees C for the given cell reaction is; -2.00 V.
To calculate the standard cell potential at 25 degrees C for the given cell reaction, we need to use the following equation;
E°cell = E°red, cathode - E°red, anode
where E°red, cathode is the standard reduction potential for the reduction half-reaction occurring at the cathode, and E°red, anode is the standard reduction potential for the reduction half-reaction occurring at the anode.
The half-reactions for the given cell reaction are;
Cathode; Cu²⁺(aq) + 2e⁻ → Cu(s)
Anode; Al³⁺(aq) + 3e⁻ → Al(s)
Using the standard free energies of formation (ΔG°f) for each species in Appendix C, we can calculate the standard reduction potentials (E°red) for each half-reaction using the following equation;
ΔG° = -nFE°red
where n is number of electrons transferred in the half-reaction, F is Faraday constant (96,485 C/mol), and E°red is standard reduction potential.
For the cathode half-reaction;
Cu²⁺(aq) + 2e⁻ → Cu(s)
ΔG°f(Cu²⁺(aq)) = -166.1 kJ/mol
ΔG°f(Cu(s)) = 0 kJ/mol
ΔG° = ΔG°f(Cu(s)) - ΔG°f(Cu²⁺(aq)) = 166.1 kJ/mol
n = 2 (since 2 electrons are transferred)
E°red,cathode = -ΔG°/(nF) = -0.34 V
For the anode half-reaction;
Al³⁺(aq) + 3e⁻ → Al(s)
ΔG°f(Al³⁺(aq)) = -524.2 kJ/mol
ΔG°f(Al(s)) = 0 kJ/mol
ΔG° = ΔG°f(Al(s)) - ΔG°f(Al³⁺(aq)) = 524.2 kJ/mol
n = 3 (3 electrons are transferred)
E°red,anode = -ΔG°/(nF) = 1.66 V
Therefore, the standard cell potential at 25 degrees C for the given cell reaction is;
E°cell = E°red,cathode - E°red,anode
E°cell = (-0.34 V) - (1.66 V)
E°cell = -2.00 V
The negative sign indicates that the cell reaction is not spontaneous under standard conditions.
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