The Solubility Of Fe(OH)₂ In Water At 25 °C Is Measured To Be 5.2x 10⁻⁴ Fe(OH)₂ Ksp value is 5.6 × 10⁻¹⁰.
The chemical reaction is given as follows :
Fe(OH)₂ ⇄ Fe²⁺ + 2OH⁻
Ksp expression for the given reaction is given as follows :
Ksp = [Fe²⁺] [OH⁻]²
the solubilty S = 5.2x 10⁻⁴
so , the Ksp = S × (2S)²
= 4S³
Ksp = 4 ×S³
= 4 × ( 5.2x 10⁻⁴ )³
= 4 × 140.6 × 10⁻¹²
= 5.6 × 10⁻¹⁰
The solubility product value for Fe(OH)₂ that is Ksp value is 5.6 × 10⁻¹⁰.
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What is the total mass in grams of 0.75 mole of SO2?
1
16 g
2
24 g
3
32 g
4.
48 g
Answer:
48 grams
Explanation:
The total mass in grams of 0.75 moles of SO2 is 48g.
HOW TO CALCULATE MASS:
The mass of a substance can be calculated by multiplying the moles of the substance by its molar mass. That is;mass of substance = moles × molar mass
According to this question, there are 0.75 moles of SO2.
The molar mass of SO2 = 32 + 16(2) = 64g/mol.
Mass of SO2 = 64g/mol × 0.75mol
Mass of SO2 = 48g
Therefore, the total mass in grams of 0.75 moles of SO2 is 48g.
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One student made the incomplete diagram shown below to represent the relationship between Magma, Igneous Rocks, and Metamorphic Rocks.
Which of these is the correct next step to complete the diagram?
A. Put an arrow labeled deposition and lithification, pointing from Igneous Rocks to Magma.
B. Put an arrow labeled heat and pressure, pointing from Magma to Igneous Rocks.
C. Put an arrow labeled heat and melt, pointing from Metamorphic Rocks to Magma.
D. Put an arrow labeled cools and crystallizes, pointing from Igneous Rocks to Metamorphic Rocks.
Answer:
the answer is B
Explanation:
this shows the next step and shows how magma turns into igneous rocks by heat and pressure
The tomato is dropped. What is the velocity, v
, of the tomato when it hits the ground? Assume 86.0 %
of the work done in Part A is transferred to kinetic energy, E
, by the time the tomato hits the ground.
Express your answer with the appropriate units.
To determine the tomato's velocity when it hits the ground, we need more information. Specifically, we need the height from which the tomato was dropped and the tomato mass.
Without these details, it is impossible to calculate velocity accurately. The velocity of an object when it hits the ground depends on factors such as the height of the fall, the mass of the object, and any forces acting on it during the fall (such as air resistance).
If you can provide the necessary information, I can help you calculate the velocity of the tomato when it hits the ground.
While out camping one spring night, you think the moon looks orange. What is one possible explanation?
A
The moon is in its orange phase.
B
The sun is orange, and the moon is reflecting its reddish light.
C
The moon itself is giving off an orange light.
D
The dust in the atmosphere makes the moon appear orange.
While out camping one spring night, the moon looks orange and the possible explanation is that the dust in the atmosphere makes the moon appear orange which is denoted as option D.
What is Moon?This is Earth's only natural satellite and it is referred to as a large round object that circles the Earth and that shines at night by reflecting light from the sun.
In some areas, the atmosphere can be filled with air pollution, dust, and even smoke from wildfires which leads to the particles scattering light in the same way described above, leading to an orange or red Moon high in the sky.
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How many years passed between the first man on the Moon and the first US woman in space?
It took 14 years between the first man on the Moon and the first US woman in space.
What is space exploration?The use of astronomy and space technology to explore outer space is known as space exploration. While astronomers use telescopes to explore space, physical exploration is carried out by both uncrewed robotic space probes and human spaceflight.
Understanding gravity, the magnetosphere, the atmosphere, fluid dynamics, and the geological evolution of other planets, for example, has come from studying the solar system.
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Experiment 4: A chemist mixes aqueous solutions of sodium hydroxide and aluminum chloride in a double-displacement reaction, which forms a white solid precipitate and a clear solution. Write the complete, balanced molecular equation for the reaction. Include physical states.
balanced equation:
The balanced molecular equation for the reaction between sodium hydroxide (NaOH) and aluminum chloride (\(AlCl_3\)) in aqueous solution can be written as follows: 2NaOH(aq) + 3\(AlCl_3\)(aq) → 3NaCl(aq) + \(Al(OH)_3\)(s)
In this reaction, sodium hydroxide (NaOH) reacts with aluminum chloride (\(AlCl_3\)) to form sodium chloride (NaCl) and aluminum hydroxide (\(Al(OH)_3\)). The coefficients in the balanced equation indicate the stoichiometric ratio between the reactants and products.
The physical states of the substances are indicated by the symbols (aq) for aqueous solutions and (s) for the solid precipitate.
The reaction is a double-displacement reaction, also known as a precipitation reaction. Double-displacement reactions involve the exchange of ions between two compounds, resulting in the formation of a precipitate.
In this case, sodium hydroxide and aluminum chloride react to form sodium chloride and aluminum hydroxide, with aluminum hydroxide being the white solid precipitate.
It's worth noting that the actual reaction might involve hydrated forms of the compounds, such as NaOH·x\(H_2O\) and \(AlCl_3\)·y\(H_2O\). However, for simplicity, these hydrated forms are not included in the balanced equation.
Overall, the balanced equation represents the chemical reaction between sodium hydroxide and aluminum chloride, showing the reactants, products, and their stoichiometric ratios.
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How many moles of lithium hydroxide are required to react with 19.2 mol CO2, the average amount exhaled by a person each day?
Answer:
38.4 mol LiOH
Explanation:
Step 1: Write the balanced neutralization equation
2 LiOH + CO₂ ⇒ Li₂CO₃ + H₂O
Step 2: Establish the appropriate molar ratio
According to the balanced equation, the molar ratio of LiOH to CO₂ is 2:1.
Step 3: Calculate how many moles of lithium hydroxide are required to react with 19.2 mol CO₂
19.2 mol CO₂ × 2 mol LiOH / 1 mol CO₂ = 38.4 mol LiOH
Which of the following will decrease the pressure of a gas in a closed container?
A. increasing the number of molecules
B. increasing the amount of light
C. increasing the temperature
D. increasing the volume
please answer asap thank you :))
Increasing the number of molecules will decrease the pressure of a gas in a closed container. Hence, option A is correct.
What is pressure?Pressure, in the physical sciences, the perpendicular force per unit area, or the stress at a point within a confined fluid.
An increase in the number of gas particles in the container increases the
frequency of collisions with the walls and therefore the pressure of the gas.
If the temperature decreases the pressure will also decrease.
Temperature is a measure of kinetic energy. When the temperature inside the container decreases the kinetic energy will also decrease.
Hence, option A is correct.
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Na2S(aq)+CaCl2(aq)For the following problem determine the products, if the forms a precipitate and balance it.
Answer:
Explanation:
Here, we want to get the resulting products from the combination of the reactants
The products formed are sodium chloride and calcium sulfide
The calcium sulfide is insoluble and it is the precipitate formed
We have the equation of reaction as follows:
\(Na_2S_{(aq)}+CaCl_{2(aq)}\text{ }\rightarrow CaS_{(s)}+2NaCl_{(aq)}\)A 25 ml sample of 1.2 molar potassium chloride mix with 15 ml of 0.90 molar barium nitrate solution and precipitate reaction occurs twice case LX + BA no3s aqueous bacl2 solid + 2ks what is the practical yield percentage yield mass is 2.45 g
Which statements explain why theories change over time? Check all that apply.
Scientists change the definition of theory to have their ideas accepted.
New information and technology may be developed that influence the theory.
Theories change with each new generation of scientists.
New experimental methods provide new information.
Theories may or may not be supported by new information.
The following are true about a theory;
New information and technology may be developed that influence the theory.New experimental methods provide new information.Theories may or may not be supported by new information.What is a theory?A theory is an explanation that is given to a phenomenon which may have some kind of underpinning reasoning that may not necessarily be empirical. Thus a theory has withstood some kind of scrutiny but is not yet absolutely accepted as true.
Thus the following are true about theory;
New information and technology may be developed that influence the theory.New experimental methods provide new information.Theories may or may not be supported by new information.Learn more about theory:https://brainly.com/question/1759635
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Select the correct answer from each drop-down menu.
B is metamorphism
A is Cementation
What are the processes in the rock cycle?The main processes in the rock cycle are:
Weathering: This is the physical or chemical breakdown of rocks into smaller fragments by natural forces such as wind, water, and ice. Weathering can occur through mechanical weathering (e.g. freeze-thaw cycles, abrasion, and root action) or chemical weathering (e.g. oxidation, hydrolysis, and carbonation).
Erosion: This is the process by which weathered materials are transported and removed from their original location by agents such as water, wind, or ice.
Deposition: This is the process by which sediments or rocks are laid down or deposited in a new location after being transported by erosion.
Compaction: This is the process by which sediments are squeezed and packed together by the weight of overlying sediments, which causes them to become more tightly packed and solid.
Cementation: This is the process by which minerals in the groundwater (e.g. silica, calcite, or iron oxide) precipitate out of solution and bind the sediments together into solid rock.
Metamorphism: This is the process by which rocks are subjected to high temperatures, pressures, and chemical reactions that change their physical or chemical properties, resulting in the formation of metamorphic rocks.
Melting and solidification: This is the process by which rocks are melted by high temperatures, and then cooled and solidified to form igneous rocks.
By undergoing these processes, rocks can be transformed from one type to another over time, in a cyclical process that repeats itself over millions of years.
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Which of the atoms listed below has the largest radius?
A) AI
B) P
C) Si
D) Na
E) Mg
According to the given statement Na of the atoms listed below has the largest radius.
What is an atom?An atom is made up of a core nucleus and one or even more electrons with negative charges that orbit it. The positively charged, comparatively hefty protons and neutrons that make it up the nucleus may be present. The fundamental building components of matter are atoms.
How are atoms made?Atoms are made up of a nucleus in the center that is surrounded by protons, neutrons, and electron. Uranium is divided into smaller atoms during the fission process, creating new atoms. The creation or atoms in enormous numbers can be seen in the Big Bang and Supernova phenomena.
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Insert the term that correctly completes the paragraph.
Illustration of a rock showing that the layers are not stacked horizontally and look like a rainbow of layers.
Soledad studied rocks and how they help show the history of Earth. She knew that scientists use different ways to find out how old rock layers are and recognized one such example in the rock in the image. The image is an example of a/an
rock.
Gravity causes spacecraft such as stars, planets, moons, and other bodies to orbit one another. Revolution describes this style of movement.
What is Gravity ?Gravity causes spacecraft such as stars, planets, moons, and other bodies to orbit one another. Revolution describes this style of movement. Space is also home to several stationary things. Rotation describes this movement.We experience day and night because of how long it takes the Earth to complete one rotation. A year is the length of one Earth rotation around the sun. Due to their varying rates of rotation and revolving, other planets have days and years that differ from our own.In the same direction, every planet in our solar system orbits the sun. In addition, the majority of them rotate in the same direction (with the exception of Venus and Uranus). In the cosmos, approximately half of all galaxies rotate in a clockwise direction, and the other half in a counterclockwise direction. This may be due to the manner that the cosmos started, according to scientists.To Learn more About Gravity refer To:
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3. A Wilkinson’s catalyst is widely used in the hydrogenation of alkenes. Show a catalytic cycle, including: i. chemical structure of the catalyst, with complete stereochemistry ii. molecular geometry of catalyst iii. type of reactions involved iv. the appropriate starting material, reagent and solvent v. major and minor end-products vi. all intermediates, for each reaction stated in (iii)
We can see here that the catalytic cycle for the hydrogenation of alkenes using Wilkinson's catalyst involves several steps.
What are the steps involved?Here's an overview of the catalytic cycle, including the necessary details:
i. Chemical structure of the catalyst:
Wilkinson's catalyst, also known as chloridotris(triphenylphosphine)rhodium(I), has the following chemical structure: [RhCl(PPh3)3]
ii. Molecular geometry of the catalyst:
The Wilkinson's catalyst has a trigonal bipyramidal geometry around the rhodium center. The three triphenylphosphine (PPh3) ligands occupy equatorial positions, while the chloride (Cl) ligand occupies an axial position.
iii. Type of reactions involved:
The catalytic cycle involves several reactions, including:
Oxidative addition: The rhodium center undergoes oxidative addition, reacting with molecular hydrogen (H2) to form a dihydride intermediate.Alkene coordination: The alkene substrate coordinates to the rhodium center, forming a π-complex.Hydrogenation: The coordinated alkene undergoes hydrogenation, resulting in the addition of hydrogen atoms to the double bond and formation of a metal-alkyl intermediate.Reoxidation: The metal-alkyl intermediate reacts with a hydrogen molecule to regenerate the rhodium dihydride species.iv. Starting material, reagent, and solvent:
The starting material is an alkene, and the reagent is Wilkinson's catalyst ([RhCl(PPh3)3]). The reaction is typically carried out in a suitable solvent, such as dichloromethane (CH2Cl2) or tetrahydrofuran (THF).
v. Major and minor end-products:
The major end-product of the hydrogenation reaction is the fully saturated alkane, resulting from the addition of hydrogen across the double bond. The minor end-product may include cis- or trans-configured alkanes if the original alkene substrate possesses geometric isomers.
vi. Intermediates:
The intermediates in the catalytic cycle include:
Rhodium dihydride complex: [RhH2(PPh3)3]Alkene-Rhodium π-complex: [Rh(η2-alkene)(PPh3)3]Metal-alkyl intermediate: [Rh(alkyl)(PPh3)3]These intermediates play a crucial role in facilitating the hydrogenation reaction and enabling the catalytic cycle to proceed.
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What is the mass (in g) of a solid piece of iron which has a specific heat of 0.449 J/g°C if when it absorbed 948.0 J of heat the temperature rose from 24.0°C to
82.1°C? Give your answer in 3 sig figs.
Answer:
Explanation:
We can use the formula:
q = mcΔT
where q is the heat absorbed, m is the mass, c is the specific heat, and ΔT is the change in temperature.
Given:
specific heat of iron (c) = 0.449 J/g°C
initial temperature (T1) = 24.0°C
final temperature (T2) = 82.1°C
heat absorbed (q) = 948.0 J
Substituting the given values into the formula, we get:
q = mcΔT
948.0 J = m(0.449 J/g°C)(82.1°C - 24.0°C)
948.0 J = m(0.449 J/g°C)(58.1°C)
m = 948.0 J ÷ (0.449 J/g°C × 58.1°C)
m = 33.1 g
Therefore, the mass of the iron piece is 33.1 g (to three significant figures)
When sodium (na) and chlorine (cl) are combined, a small amount of table salt is formed and a bright yellow light and a lot of heat are given off. Does it take more energy to break the bonds of the reactants, or is more energy released when forming the bonds of the products? how do you know?(1 point).
Since a lot of heat is produced during the bond- forming process of the products, further energy is released during that process than is frequently the case.
A more accurate dimension of energy use and position is thermal energy. As bonds are broken in the reactants during exothermic processes, further energy is released when the bonds are created in the products. An increase in the response admixture's temperature is a specific of exothermic responses. The term" endothermic" refers to chemical responses that generally absorb( or use) energy. When bonds in the reactants are broken, further energy is absorbed than is released when new bonds are generated in the products. This is known as an endothermic response. As the response's temperature drops, endothermic processes are endothermic.
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It takes more energy to break the bonds of the reactants than to form the bonds of the products. This is because of the Law of Conservation of Energy,
Which states that energy cannot be created or destroyed, only transferred from one form to another. When the reactants undergo a chemical reaction, the bonds between the atoms break and the energy that was stored in those bonds is released in the form of heat and light. This energy is then used to form the bonds between the atoms of the products. This process requires less energy than the breaking of the bonds of the reactants, so overall more energy is released than was used to break the bonds.
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An element has 2 stable isotopes. One has 13 amu and 1.07% abundant . The second has 12 amu and 98.93% abundant. What is the average atomic mass of the element
The average atomic mass of the element is 12.0107 amu.
To calculate the average atomic mass of the element in question, we can use the following formula:
average atomic mass = (mass of isotope 1 x abundance of isotope 1) + (mass of isotope 2 x abundance of isotope 2)
where "mass of isotope 1" is the mass of the first stable isotope (13 amu in this case), "abundance of isotope 1" is the percentage of that isotope in the element (1.07% in this case), "mass of isotope 2" is the mass of the second stable isotope (12 amu in this case), and "abundance of isotope 2" is the percentage of that isotope in the element (98.93% in this case).
Substituting the given values in the formula, we get:
average atomic mass = (13 amu x 1.07%) + (12 amu x 98.93%)
average atomic mass = (0.1391 amu) + (11.8716 amu)
average atomic mass = 12.0107 amu
Therefore, the average atomic mass of the element is 12.0107 amu.
This means that on average, one atom of this element weighs 12.0107 atomic mass units (amu), which is slightly heavier than the most abundant isotope (12 amu) due to the presence of the less abundant isotope (13 amu). This concept is important in chemistry because the mass of atoms plays a crucial role in determining their chemical and physical properties. The knowledge of the average atomic mass of an element is important in a wide range of applications, including analytical chemistry, geochemistry, and nuclear physics.
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HCl(aq) + KOH(aq) → KClaq) + H2O(1)
Answer:
yes the equation is correct and balanced
Nuclei with an even number of protons and an even number of neutrons are more stable than those with an odd number of protons and/or an odd number neutrons. What is the significance of the even number of protons and neutrons in this case?
The significance of the even number of protons and neutrons, in this case, is that it gives stability to the nucleus of an atom.
What are protons are neurons?Protons are the positively-charged sub-atomic particle found in the nucleus of an atom. Protons are responsible for the mass of the atom of an element.
Protons exert a positive attractive force on the electrons found in orbitals around the atom.
Neutrons are neutral particles that are found together with the protons in the nucleus of an atom.
Neutrons together with protons account for the mass of an atom. Although neutrons are neutral, they contribute to the strong nuclear force that holds the nucleus of an atom together.
The correct ratio of protons and neutrons in the nucleus of an atom is required for the stability of the nucleus of an atom.
When the ratio of the protons and neutrons increases above 1 : 1.5, the nucleus of the atom becomes unstable.
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A runner has a mass of 60 kg and a velocity of 0 m/s. What is her momentum?
Answer:
The answer is 0 kg m/sExplanation:
The momentum of an object can be found by using the formula
momentum = mass × velocity
From the question the momentum of the runner will be 0 kgm/s since the runner's velocity is 0
Hope this helps you
Sugar
O2
CO2
H2O
What is the name of this energy pathway?
thnxx for free point? ?????????
A 1.0 L buffer solution is 0.300 M HC2H3O2 and 0.045 M LiC2H3O2. Which of the following actions will destroy the buffer?
a) Adding 0.050 moles of HC2H3O2
b) Adding 0.075 moles of HCl
c) Adding 0.0500 moles of LiC2H3O2
d) Adding 0.050 moles of NaOH
e) None of the above will destroy the buffer.
Answer:
b) Adding 0.075 moles of HCl
Explanation:
A buffer is defined as the aqueous mixture of a weak acid and its conjugate base or vice versa (Weak base with its conjugate acid).
The buffer of the problem is the acetic acid / lithium acetate.
The addition of any moles of the acid and the conjugate base will not destroy the buffer, just would change the pH of the buffer. Thus, a and c will not destroy the buffer.
The addition of an acid (HCl) or a base (NaOH), produce the following reactions:
HCl + LiC₂H₃O₂ → HC₂H₃O₂ + LiCl
The acid reacts with the conjugate base to produce the weak acid.
And:
NaOH + HC₂H₃O₂ →NaC₂H₃O₂ + H₂O
The base reacts with the weak acid to produce conjugate base.
As the buffer is 1.0L, the moles of the species of the buffer are:
HC₂H₃O₂ = 0.300 moles
LiC₂H₃O₂ = 0.045 moles
The reaction of HCl with LiC₂H₃O₂ consume all LiC₂H₃O₂ -because there are an excess of moles of HCl that react with all LiC₂H₃O₂-
As you will have just HC₂H₃O₂ after the reaction, the addition of b destroy the buffer.
In the other way, 0.0500 moles of NaOH react with the HC₂H₃O₂ but not consuming all HC₂H₃O₂, thus d doesn't destroy the buffer.
What sample at STP has the same number of molecules as 5 L of NO2
Answer:
5l NO
2
at STP
No. of molecules=
22.4
5
mol=
22.4
5
×N
A
molecules
A) 5ℊ of H
2
(g)
No. of moles=
2
5
mol=
2
5
×N
A
molecules
B) 5l of CH
4
(g)
No. of moles of CH
4
=
22.4
5
mol=
22.4
5
N
A
molecules
C) 5 mol of O
2
=5N
A
O
2
molecules
D) 5×10
23
molecules of CO
2
(g)
Molecules of 5l NO
2
(g) at STP=5l of CH
4
(g) molecules at STP
Therefore, option B is correct.
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Combined Gas Law equation is represented by
A)T1 / P1V1 = T2 / P2V2
B) P1V1 / T1 = P2V2 / T2
C)P1V1 / T1 = (P2V2 / T2)2
D)PV = nRT
The combined Gas Law equation is represented by B) P1V1 / T1 = P2V2 / T2.
The combined gas law is the law that combines Charles’s law, Gay-Lussac’s law, and Boyle’s law.
Combined gas law can be mathematically expressed as
k = PV/T
Where,
P = pressure
T = temperature in kelvin
V = volume
K = constant (units of energy divided by temperature)
When two substances are compared in two different conditions, the law can be stated as,
P1V1/T1 = P2V2/T2
Where,
P1 = initial pressure
V1 = initial volume
T1 = initial temperature
P2 = final pressure
V2= final volume
T2 = final temperature
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The measure of the length of events and the duration of intervals between events
The measure of the length of events and the duration of intervals between events is time.
What is time?The duration of events or the gaps between them can be measured, compared, or even ordered using time. The lengthy period of time that the Earth's geologic history takes up is known as geologic time. Starting at the beginning of the Archean Eon formal geologic time runs until the present. Geology is defined as the "Science of the Earth."
Geology is the fundamental Earth science that examines how the earth created, its structure and composition, and the various forces acting on it. It is sometimes known as geoscience or earth science.
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Question 4 (1 point)
If the decomposition of (NH4)2(CO3) is a first-order process with a rate constant of
0.196 s-1, how much ammonium carbonate would remain after 39.0 s, starting from
a concentration of 0.957 M?
Your Answer in units:
The final concentration of the reactant of a first order reaction can be determined from the rate constant equation. The concentration of ammonium carbonate after 39 s will be 0.003 M.
What is rate constant?Rate constant of a reaction is the rate of reaction when one molar concentration of the reactant is involved in the reaction. The expression for the rate constant k for first order reaction is :
k = 1/t ln (C0/Ct)
Where C0 be the initial concentration and Ct be the concentration after t seconds.
Given that C0 of ammonium nitrate = 0.957 M
rate constant = 0.196 /s
t = 39 s.
The concentration after 39 seconds is calculated as follows:
0.196 /s = 1/39s ln (0.957 M / Ct)
Ct = 0.957 / (ln⁻¹ (0.196 × 39))
= 0.003 M.
Therefore, the concentration of ammonium carbonate after 39 seconds will be 0.003 M.
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What are two basic aspects of science?
The Two Aspects of Science: Control over nature and understanding of nature must both be held in equal honor.
Drag the tiles to the correct locations on the equation. Not all tiles will be used.
Two atoms interact with each other and change as shown by the equation. Complete the equation by filling in the missing parts.
5
2
4
3
1
H+H -
H
He
Li
+
The equation in the question is: H+H → H + H Complete the equation by filling in the missing parts. missing part is 1 → H+H-2 → →3 → He.
The atomic number of hydrogen is 1, which means it has only one proton in the nucleus and one electron in its shell. Two hydrogen atoms react with each other to form helium. Helium has 2 protons and 2 neutrons in its nucleus and two electrons in its shell. Therefore, the equation is:
H + H → HeIt can be seen that:1. H + H (Reactants)
2. → (Yields or Reacts to form)
3. He (Product)Therefore, the tiles will be arranged as shown below: 1 → H+H-2 → →3 → He
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eThe lab question is "Based on a substance'sproperties, how can you determine whether itsbonds are ionic or covalent?" Fill in the box toanswer this question with a hypothesis.Hypothesis: If a substance contains ionic bonds,then its properties would includeDONE
Explanation:
An ionic bond is formed between two ions, the positive one (the cation) will give an electron to the negatively charged (the anion) to complete their octets.
Ionic compounds are usually found as solid crystals, their boiling and melting points are high and they conduct electricity when they are in solution.
Answer: If a substance contains ionic bonds, then its properties would include high melting and boiling point, they would conduct electricity in solution and they can be usually found in nature as solid crystals.