explain why the amide nitrogen is much less reactive as a base towards aqueous acids than the alkylamine nitrogen. how does this experiment illustrate this?

Answers

Answer 1

The amide nitrogen is much less reactive as a base towards aqueous acids than the alkylamine nitrogen due to the presence of the carbonyl group adjacent to the nitrogen in the amide.

This carbonyl group withdraws electron density from the nitrogen, making it less basic and less likely to accept a proton from an aqueous acid. In contrast, the alkylamine nitrogen has no such electron-withdrawing group, and thus is more basic and more likely to accept a proton from an aqueous acid.
An experiment that illustrates this difference in reactivity is the acid-base titration of an amide and an alkylamine with hydrochloric acid. The amide would require a stronger acid and a longer titration time to reach its equivalence point, indicating its lower reactivity as a base towards aqueous acids. On the other hand, the alkylamine would require a weaker acid and a shorter titration time to reach its equivalence point, indicating its higher reactivity as a base towards aqueous acids.

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Related Questions

The Bergeron process causes cloud droplets to grow because
A. freezing nuclei are much more common in the atmosphere than other condensation nuclei.
B. water freezes instantly when its temperature reaches 0 degrees
C. the saturation vapor pressure is lower near ice crystals than it is near supercooled droplets.
D. larger drops fall and collect smaller droplets in the cloud.

Answers

Answer: C. the saturation vapor pressure is lower near ice crystals than it is near supercooled droplets

The Bergeron process causes cloud droplets to grow because,  the saturation vapor pressure is lower near ice crystals than it is near supercooled droplets.

What is Bergeron process ?

Physical transformations from a cloud of extremely small droplets to much bigger precipitation-sized particles that fall to the earth require a number of intricate and poorly understood physical processes.

The process of collision and coalescence, in which colliding droplets expand by merging together or coalescing, is how droplets form in warm clouds, those that solely contain liquid water.

Larger droplets pass through tiny droplets more quickly because they descend at a faster rate than the smaller ones. Strong updrafts (rising air currents) can produce cloud raindrops, just like hail, since they let heavier drops to stay suspended in the cloud.

Bergeron's process causes precipitation-sized particles to develop in cool clouds. Hence, option C is correct.

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How will you prepare hydrogen from zinc and dilute acid.​

Answers

Hydrogen is basically prepared by action of dilute acids On metals.
Dilute Hydro chloric acid is added To zinc granules. The hydrogen produced is then passed through anhydrous calcium chloride or concentrated sulphuric acid. The hydrogen collected by upward delivery because it is lighter than air. If the reaction is too slow Copper (II) Sulphate solution can be added to speed up the solution.
Zn (s)+ 2HCl (aq)———ZnCl2 (aq)+ H2(g).

what is the number of moles in 3.88 g of NO2

Answers

Answer:

0.0843 moles

Explanation:

The molar mass of NO2 is 46.0055 g/mol

To solve for the number of moles you will need to use stoichiometry.

\(\frac{3.88g}{}*\frac{1 mol}{46.0055 g} =0.084338 moles\)

Use sig figs to round.

0.0843

14n+16o+16o=46

3.88/46 = 0.0843

define hydroscopy in chemistry

Answers

Answer: A hygroscopic substance is one that readily attracts water from its surroundings, through either absorption or adsorption

Explanation:

Describe the structure of ammonium lauryl sulfate. Refer to the given diagram. Your answer should include the type of bonding, the elements contained, and the size and shape of the molecule. Write a short paragraph.

Describe the structure of ammonium lauryl sulfate. Refer to the given diagram. Your answer should include

Answers

Explanation:

Ammonium lauryl sulfate (ALS) is the common name for ammonium dodecyl sulfate (CH3(CH2)10CH2OSO3NH4). The anion consists of a nonpolar hydrocarbon chain and a polar sulfate end group. The combination of nonpolar and polar groups confers surfactant properties to the anion: it facilitates the dissolution of both polar and non-polar materials. ALS is classified as a sulfate ester. It is found primarily in shampoos and body wash as a foaming agent. Lauryl sulfates are very high-foam surfactants that disrupt the surface tension of water in part by forming micelles at the surface-air interface.

Carmen is heating some water and trying to measure the temperature of water using a celsius thermometer. which measurement can she expect once the water begins to boil? a. 32°c b. 100° cc. 212°c d. 373°c

Answers

Once the water begins to boil, Carmen can expect a measurement of 100°C on the Celsius thermometer. Option b is correct.

At standard atmospheric pressure, water boils at 100°C, which is the boiling point of water. This is the temperature at which water changes from a liquid to a gas (water vapor) as it absorbs heat energy.

Option a (32°C) is the freezing point of water, while option c (212°C) and option d (373°C) are the boiling points of water at different pressure levels. However, at standard atmospheric pressure, the boiling point of water is 100°C. Hence option b is correct choice.

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osvoldo has a goal of getting at least 30 % 300, percent of his grams of carbohydrates each day from whole grains. today, he ate 220 220220 grams of carbohydrates, and 55 5555 grams were from whole grains. did osvoldo meet his goal? why?

Answers

He did not meet his goal because 25% is lesser than 30% and he needs 30% or more Osvoldo's objective was not achieved.

If he had 220 grams of carbohydrates today, and 55 of those grams came from whole grains, then the proportion of his total carbohydrates that were made up of whole grains was.

It is assumed that Osvoldo aims to consume at least 30 percent of his daily grams of carbohydrates from whole grains.

He consumed 220 grams of carbohydrates today.

55 grams of whole-grain carbohydrates

We must ascertain whether Osvoldo achieved his objective or not.

We must determine if 55 is at least 30% of 220.

He only obtains 25% of his daily grams of carbohydrates from whole grains because 55 is 25% of 220.

55/220 × 100 = 25%

he has a goal of getting at least 30% percent of his grams of carbohydrates each day from whole grains, Hence, Osvoldo did not meet his goal.

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air is composed of nitrogen oxygen and based on that information air can be described as

Answers

Answer:

Air can be described as:  Mass and Mixture of Gases

Mass is defined as how much stuff an object contains - and by stuff, I mean matter, like atoms and molecules. And even though you can't see it, air has a lot of atoms and molecules. Air is a gas (as opposed to a liquid or a solid) and contains about 78% nitrogen, 21% oxygen, and 1% argon.

Explanation:

the rate of effusion of neon to an unknown gas is 1.89. what is the other gas?

Answers

The unknown gas could be bromine gas

To determine the other gas, we need to use Graham's Law of Effusion. According to this law, the rate of effusion of two gases is inversely proportional to the square root of their molar masses.

So, let's assume that the molar mass of neon is known and equal to 20 g/mol. We can then set up the following equation:

1.89 (rate of effusion of neon) = sqrt(Molar Mass of Unknown Gas / 20)

Solving for the molar mass of the unknown gas, we get:

Molar Mass of Unknown Gas = (1.89)^2 * 20

Molar Mass of Unknown Gas = 71.44 g/mol

Now, we need to identify which gas has a molar mass of 71.44 g/mol. This could be any gas with a molar mass close to that value, but one possible answer is bromine gas (Br2), which has a molar mass of 159.8 g/mol.

Therefore, the unknown gas could be bromine gas.
Using Graham's Law of Effusion, we can determine the identity of the unknown gas based on the given rate of effusion. The formula for Graham's Law is:

(rate of effusion of gas 1) / (rate of effusion of gas 2) = √(molar mass of gas 2) / √(molar mass of gas 1)

Since the rate of effusion of neon to the unknown gas is 1.89, we can set up the equation as follows:

1.89 = √(molar mass of unknown gas) / √(molar mass of neon)

The molar mass of neon is 20.18 g/mol. Now we need to solve for the molar mass of the unknown gas:

1.89 * √(20.18) = √(molar mass of unknown gas)

Square both sides:

(1.89²) * 20.18 = molar mass of unknown gas
7.1641 = molar mass of unknown gas

Based on the calculated molar mass, the unknown gas is likely hydrogen (H2) since its molar mass is approximately 2.016 g/mol.

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What is the nature of CX bond in alkyl halide?

Answers

Haloarenes have polarized C-X bonds because halogens are more electronegative than carbon. Halogen acquires a tiny negative charge due to its high electronegativity, whereas carbon acquires a slight positive charge by drawing the electron cloud more strongly towards it.

Only one sigma bond is created between one carbon atom and one halogen atom because halogens only require one electron to attain their closest noble gas state.

Dipole moment is a function of the electronegativity differential between halogens and carbon, and as we are aware, when halogen electronegativity drops within a group, so does the dipole moment. Dipole moments between C-Cl and C-F are an exception.

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A stick of butter is melted in a saucepan. As it continues to cook, the butter turns brown. What changes have occurred?

Answers

Answer:

Assuming that the butter is already a liquid, it is a chemical change in which the milk solids of the butter oxidize.

Explanation:

I hope this helps :)

Chemical changes have occurred as the stick of butter melts as the milk solids present in butter undergo oxidation resulting in formation of new substances.

What are chemical changes?

Chemical changes are defined as changes which occur when a substance combines with another substance to form a new substance.Alternatively, when a substance breaks down or decomposes to give new substances it is also considered to be a chemical change.

There are several characteristics of chemical changes like change in color, change in state , change in odor and change in composition . During chemical change there is also formation of precipitate an insoluble mass of substance or even evolution of gases.

There are three types of chemical changes:

1) inorganic changes

2)organic changes

3) biochemical changes

During chemical changes atoms are rearranged and changes are accompanied by an energy change as new substances are formed.

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For a particular redox reaction, NO−2 is oxidized to NO−3 and Cu2+ is reduced to Cu+ . Complete and balance the equation for this reaction in basic solution. Phases are optional. balanced redox reaction: NO−2+Cu2+⟶NO−3+Cu+ NO 2 − + Cu 2 + ⟶ NO 3 − + Cu +

Answers

In order to balance the redox reaction of NO−2 oxidized to NO−3 and Cu2+ reduced to Cu+ in basic solution, you need to follow the following Write the unbalanced half-reactions Oxidation half-reaction: NO−2 ⟶ NO−3 Reduction half-reaction.

Balance the number of atoms on each half-reaction: Oxidation half-reaction: 3NO−2 ⟶ 3NO−3Reduction half-reaction: Cu2+ ⟶ Cu+ Balance the number of electrons on each half-reaction:Oxidation half-reaction: 3NO−2 ⟶ 3NO−3 + 6e-Reduction half-reaction: Cu2+ + 2e- ⟶ Cu+ Equalize the number of electrons for the oxidation and reduction half-reactions. The reduction half-reaction involves 2 electrons and the oxidation half-reaction involves 6 electrons. To equalize these, multiply the reduction half-reaction by This results in:Oxidation half-reaction: 3NO−2 ⟶ 3NO−3 + 6e-Reduction half-reaction .

Combine both half-reactions into one equation:3NO−2 + 3Cu2+ ⟶ 3NO−3 + 3Cu+ Balance the atoms by adding water molecules to balance the oxygens and hydrogen ions (H+) to balance the hydrogens. Since the reaction is in basic solution, add OH- ions to balance the hydrogen ions.

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: Which type of line is shown on the map? isobar
isotherm
radar
humidity ​

: Which type of line is shown on the map? isobar isotherm radar humidity

Answers

The correct answer is isobar

Answer:

isobar

Explanation:

edge 23

Workers digging a tunnel through a city find some
ancient pots decorated with geometric designs.
Which of the following tasks might they ask a
chemist to do? Explain your answer.
a. Determine the materials used to make the pots.
b. Explain what the designs on the pots represent.
c. Recommend how to store the pots to prevent
further damage.

Workers digging a tunnel through a city find someancient pots decorated with geometric designs.Which

Answers

Answer:

a. Determine the materials used to make the pots.

Explanation:

Workers digging a tunnel through a city who find some ancient pots decorated with geometric designs will employ the services of a chemist.

The chemist would help to determine the materials which were used to make the pots . This is usually done by various type of experiments and observations. After the constituent of the pot is gotten then more information would be derived from the possible source and use of the pot

Each year, the Department of Water Works measures the chloride concentration level in the water. The first year, they found the chloride concentration changed by −135 mg/L . It is estimated that the chloride concentration will change −2115 mg/L the next year.

What is the total change that will likely occur in 2 years?

Enter your answer as a simplified mixed number in the box.


mg/L

Answers

The total change in 2 years is likely to be -3 2/3mg/L.

What is the total change?

Here given that ,

They discovered that the chloride concentration changed by -1 3/5 mg/L the first year.

The chloride concentration is expected to change in -2 1/15mg/L over the next year.

To determine: What is the total change that is likely to occur in two years?

To find the solution,

During the first year, the chloride concentration changed by -1 1/3

= -8/5mg/L.

The chloride concentration will change in -2 1/15 = -31/15 mg/L  over the next year.

The total change that is likely to occur in the next two years is

-8/5 + (-31/15)

= (-24 - 31 ) / 15

= -55/15

= -11/3

-3 2/3mg/L in a mixed fraction.

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system of equations You and your friend are making 30 liters of sodium water. You have liters of 10% sodium and your friend has liters of 22% sodium. How many of your liters and how many of your friend's liters should you mix to make 30 liters of 15% sodium

Answers

Answer:

X liters of 10% + (30 - x) liters of 22% = 30...

Analyzing a company's _______ ratio is one way in which an investor can tell if the company can pay off its short-term debts if there is a drop in sales revenue. acid test activity current leverage (debt)

Answers

Analyzing a company's "acid test" ratio is one way in which an investor can tell if the company can pay off its short-term debts if there is a drop in sales revenue.

The acid test ratio, also known as the quick ratio, measures a company's ability to meet its immediate financial obligations without relying on the sale of inventory. It is calculated by dividing the sum of a company's cash, cash equivalents, and accounts receivable by its current liabilities. A higher acid test ratio indicates a greater ability to cover short-term debts, which is particularly important during times of reduced sales revenue.

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5 predict whether aqueous solutions of the following compounds are acidic, basic, or neutral: (a) nh4br, (b) fecl3, (c) na2c03, (d) kci04, (e) nahcz04.

Answers

\(NH_{4} Br ,FeCl_{3}\) are acidic, \(Na_{2} CO_{3}, NaHC_{2} O_{4}\) is basic and \(KClO_{4}\) is neutral.

The salt which upon hydrolysis form strong acid and weak base it's aqueous solution is acidic, and the salt which on hydrolysis gives strong base and weak acid it's aqueous solution is basic. So -

\(NH_{4} Br + H_{2} O- > NH_{4}OH+HBr\) , HBr is a strong acid.

\(Na_{2}CO_{3} +H_{2}O- > NaOH+ H_{2}CO_{3}\),NaOH is a strong base.

And the salt which upon hydrolysis form a strong acid and strong base is neutral,\(KClO_{4}\)

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Calculate number of moles in
3.01 X 10^23 atom of moles
of rubidium

Answers

Answer:

There are 0.5 moles of rubidium

Explanation:

According to avogadro's law, 1 mole of every substance occupies 22.4 L at STP and contains avogadro's number 6.023\times 10^{23}6.023×10

23

of particles.

To calculate the moles, we use the equation:

\text{Number of moles}=\frac{\text{Given atoms}}{\text {avogadro's number}}=\frac{3.01\times 10^{23}}{6.023\times 10^{23}}=0.5molesNumber of moles=

avogadro’s number

Given atoms=

6.023×10

23

3.01×10

23

=0.5moles

Thus there are 0.5 moles of rubidium

temperature to the nearest degree

temperature to the nearest degree

Answers

Answer:

102 C

Explanation:

L. Complete this nuclear equation for the alpha decay of Uus-294 by writing a
notation for the missing product:

L. Complete this nuclear equation for the alpha decay of Uus-294 by writing anotation for the missing

Answers

The nuclear equation for the alpha decay of Uus-294 is

\(^{294}{117} Uus\) →\(^{4}{2}He + ^{290}_{115}Mc\)

To complete the nuclear equation for the alpha decay of Uus-294, we need to determine the missing product.

During alpha decay, the emission of an alpha particle, composed of two protons and two neutrons, leads to the formation of a new nucleus.

The balanced nuclear equation for the alpha decay of Uus-294 can be represented as follows:

\(^{294}{117} Uus\) → \(^{4}{2}He +\)_____(missing product)

In this equation, the atomic number of the missing product must be two less than the atomic number of Uus-294 (117 - 2 = 115), and the mass number of the missing product must be four less than the mass number of Uus-294 (294 - 4 = 290).

Based on this information, the missing product can be identified as:

\(^{290}_{115}Mc\)

Mc stands for Moscovium, which has an atomic number of 115. By subtracting two from the atomic number of Uus, we obtain the atomic number of Mc. The mass number of Mc-290 is obtained by subtracting four from the mass number of Uus-294.

Therefore, the  nuclear equation for the alpha decay of Uus-294 is:

\(^{294}{117} Uus\)→ \(^{4}{2}He + ^{290}_{115}Mc\)

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The complete question is :

Complete this nuclear equation for the alpha decay of Uus-294 by writing a

notation for the missing product:

\(^{204} {117} Uns\)→\(^{4} _{2} He +\)_____

The unit of radioactive exposure is given by a. grams b. rems c. ppm d. ppb '

Answers

The unit of radioactive exposure is given by (b) rems. The rem (Roentgen equivalent man) is a unit of measurement used to quantify the amount of radiation dose absorbed by living tissue. It takes into account the biological effects of different types of radiation on human health.

The unit of grams (a) is a measure of mass and is not specifically related to radiation exposure.

PPM (c) stands for parts per million, which is a unit used to express the concentration of a substance in a mixture. It does not directly measure radiation exposure.

Similarly, PPB (d) stands for parts per billion and is also a unit of concentration, not radiation exposure.

Therefore, the correct unit for measuring radioactive exposure is (b) rems.

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Using the balanced equation below, how many grams of cesium fluoride would be required to make 73.1 g of cesium xenon heptafluoride?

CSF + XeF6 → CsXeF7

Answers

Answer:

27.9 g

Explanation:

CsF + XeF₆ → CsXeF₇

First we convert 73.1 g of cesium xenon heptafluoride (CsXeF₇) into moles, using its molar mass:

Molar mass of CsXeF₇ = 397.193 g/mol73.1 g CsXeF₇ ÷ 397.193 g/mol = 0.184 mol CsXeF₇

As 1 mol of cesium fluoride (CsF) produces 1 mol of CsXeF₇, in order to produce 0.184 moles of CsXeF₇ we would need 0.184 moles of CsF.

Now we convert 0.184 moles of CsF to moles, using the molar mass of CsF:

Molar mass of CsF = 151.9 g/mol0.184 mol * 151.9 g/mol = 27.9 g

The solubility of potassium sulfate in water is 16 grams per 100
milliliter at 50 degrees centigrade. The smallest amount of water
which will dissolve 4 grams of this substance at the same temperature
will be

Answers

The answer is 25 grams for this question


You have a graduated cylinder with 20 ml. of water in it. You add 25 g of lead weights, and the volume rises to 42 ml. What is the density of lead? (No links allowed)

Answers

You have a graduated cylinder with 20 ml. of water in it. You add 25 g of lead weights, and the volume rises to 42 ml.  the density of lead is 1.13 g/mL.

given data :

mass = 25 g

initial volume , V1 = 20 mL

final volume , V2 = 42 mL

volume = V2 - V1 = 42 mL - 20 mL

volume = 22 mL

density is given as :

Density = mass / volume

density = 25 g / 22 mL

density = 1.13 g/mL

Thus, You have a graduated cylinder with 20 ml. of water in it. You add 25 g of lead weights, and the volume rises to 42 ml.  the density of lead is 1.13 g/mL.

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Suppose it takes 5 minutes for half of your sample to radioactively decay. If you started with 80 atoms, and have only 5 radioactive atoms left, how many half-lives have occurred?

Answers

4 half lives. If half decay each five minutes 80/2=40 40/2=20 20/2=10 10/2=5

CttIve Flellpitation Describe and Predict Selective Precipitation Question Which of the following is a potential application of selective precipitation? Select all that apply Select all that apply: qualitative analysis Purification or waste treatment Reaction catalysis Energy storage

Answers

Qualitative analysis and Purification are potential application of selective precipitation

Define selective precipitation

Utilizing a reagent that precipitates one or more ions while leaving others in solution, selective precipitation is a method for separating ions in an aqueous solution.

Analysis of Metallic Elements' Qualities. The ions in a mixture are separated during qualitative analysis via selective precipitation.

Selective protein precipitation can be used to fractionate a portion of proteins from a protein solution, recover a single protein of interest from a purification phase, or recover the majority of the proteins from a crude lysate in a bulk manner.

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CsH16 +12028CO2 +8H₂O
What is the ratio of octene (C8H16) to
oxygen in the reaction?

Answers

The ratio of octene to oxygen is 1:12.

To determine the ratio of octene (C8H16) to oxygen (O2) in the given reaction, we need to examine the balanced chemical equation. However, the equation you provided does not seem to be balanced. The coefficients for each compound must be determined to achieve a balanced equation before we can calculate the desired ratio.

Assuming you meant the combustion reaction of octene, a balanced equation would be:

C8H16 + 12O2 → 8CO2 + 8H2O

From the balanced equation, we can see that for every 1 mole of octene (C8H16), we require 12 moles of oxygen (O2) to completely react.

This means that for every 1 mole of octene, we need 12 moles of oxygen to fully combust the octene and produce the corresponding amounts of carbon dioxide (CO2) and water (H2O) as shown in the balanced equation.

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Hi! I don’t understand example 2. Why is the valence electronic configuration ns^2 np^2 ?

Hi! I dont understand example 2. Why is the valence electronic configuration ns^2 np^2 ?

Answers

Answer:

the largest increase is between for class 8 and 5 plus s i near station energy because this is much stronger electrostatic attraction between the intermolecular the forces joined at a point which is called electronic configuration

It takes more energy to remove core electrons than valence electrons.

This is because core electrons, being closer to the nucleus, experience greater effective nuclear charge (ENC) because of fewer filled shells shielding them from the nucleus.

What is ionisation energy (IE)?

the minimum amount of energy needed to remove a valence electron from a gaseous atom or ion forming a gaseous cation of a higher oxidation numberA greater attraction between the electron and the nucleus results in a greater ionisation energy.1st IE is the minimum energy needed to remove the 1st electron from a gaseous atom, while the 2nd IE is the minimum energy needed to remove the 2nd electron form a gaseous ion (note that it is not the removal of 2 electrons)

Example 2

Knowing that the difference 4th and 5th ionisation energies is much larger, we can imply that this difference is caused by removing a core electron instead of a valence electron. This means that there are 4 valence electrons (as removing the 1st to 4th electrons are valence electrons while the 5th electron is a core electron).

Elements with 4 valence electrons lie in group IVA (also known as group 14) of the periodic table (such as carbon and silicon). We do not know which period the element is in thus the valence electronic configuration would be written as ns²np², where s² represents the 2 elements in the s block before the element, and p² shows that it is the 2nd element in the p block. n is the period number which we do not know.

In the attached periodic table, the s block, d block, and p block are in yellow, blue and purple respectively.

Writing electronic configuration

Let's look at an example! The valence electronic configuration of Arsenic would be 4s²3d¹⁰4p³. On the other hand, the electronic configuration would be 1s²2s²2p⁶3s²3p⁶4s²3d¹⁰4p³ or [Ar]4s²3d¹⁰4p³, since Argon is the closest noble gas that comes before Arsenic. Writing electronic configuration is done according to Aufbau principle, and this is simplified in the periodic table attached where you can count accordingly reading and counting from left to right of the periodic table then down. The number of elements in a certain block is written as a superscript.

Aufbau principle

states that electrons fill orbitals of lowest sub energy level to capacity before filling orbitals of higher sub energy levels (see the 2nd attached picture)

Maximum number of electrons each subshell can hold

s subshell ➮ 2p subshell ➮ 6d subshell ➮ 10
Hi! I dont understand example 2. Why is the valence electronic configuration ns^2 np^2 ?
Hi! I dont understand example 2. Why is the valence electronic configuration ns^2 np^2 ?

Which of the following is a physical change?

Dissolving salt in water

Digesting food

Burning wood

Oxidation

Answers

Digesting Food

Explanation I Just Know
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