The control allowed me to have a point of reference in which no change should have occurred. If the control solution changed color, I would conclude there were organisms in the water.
The purpose of using change management is to overcome unpredictability and minimize undesirable project consequences. Project managers can use change management processes to determine whether a project is on budget improve team productivity and measure progress.
Change control procedures typically require two documents. Change Request: A change request document details the change and initiates the change control procedure. Project managers can use change management processes to determine whether a project.
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When an organism eats food, energy becomes available for metabolic activities. In the process, some energy enters the environment as heat. According to the Law of Conservation of energy …a) energy which is given off as heat is not part of the total energy budget of the system b) some energy is lost; as no metabolic process is 100% efficient c) no energy is lost; the total amount of energy remains the samed) energy which is not immediately used by the organism cannot be stored and is lost
Answer
C) no energy is lost; the total amount of energy remains the same.
Explanation
The law of conservation of energy states that "The energy can neither be created nor destroyed - only converted from one form of energy to another." Therefore some energy will be used for metabolism while the other can be used for other properties and some can be stored.
How many rh atoms would have to be placed side by side to span a distance of 6.0?
24074 (Rh) atoms would have to be placed side by side to span a distance of 6.0.
What is Atom?The smallest piece of matter that exists in the universe is an atom. Atoms that are neutral or ionized make up every material in our environment. The atoms are tiny, spherical objects, and the Armstrong unit is used to measure their diameter.
1A = (10^-10)
According to the given information :The diameter of a rhodium atom (Rh) is approximately d = 2.7 x 10^-10
so,
It is assumed that if we keep n atoms next to one another, we will create a distance of L = 6.5μm = 6.5 x 10^-6
In this case,
We can see that if we keep the atoms side by side, the total length of them will be determined by adding the total diameters.
we have:
L = n d
n = L/d
Putting values :
n = (6.5 x 10^-6)/( 2.7 x 10^-10)
n = 24074
24074 (Rh) atoms would have to be placed side by side to span a distance of 6.0
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Using reliable internet resources, identify ways we use radio waves on Earth.
Answer:
Ways we use radio waves on Earth are television and FM and AM radio broadcasts, military communications, mobile phones, ham radio, wireless computer networks, and numerous other communications applications.
Explanation:
Ways we use radio waves on Earth are television and FM and AM radio broadcasts, military communications, mobile phones, ham radio, wireless computer networks, and numerous other communications applications.
What are radio waves?An electromagnetic wave of a frequency between about \(10^4\) and \(10^{11}\)or \(10^{12}\) Hz, as used for long-distance communication.
AM and FM Radio Broadcasting which involves transmitting sound to a wide audience.
Radar is a detection system that uses radio waves to get information about objects.
Bluetooth and wireless communication use radio waves to create connections between devices.
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Given the equilibrium system at 25°C:NH4Cl(s) = NH(aq) + Cl(aq)(AH = +3.5 kcal/mole)Which change will shift the equilibrium to the right?
Explanation
NH4Cl(s) = NH4+(aq) + Cl-(aq) AH = +3.5 kcal/mole
We have some changes that shift the equilibrium to the right, according to Le Châtelier's principle.
I will write some of them:
By Adding amount of NH4Cl or by increasing the temperature because according to the heat of the reaction this is an endothermic reaction.
Answer: Increasing the temperature of the system.
Every Methane molecule looks different. True or false?
please use vocabulary that i can understand
Answer:
False
Explanation:
Molecules of the same substance are made up of the same type of atoms and look exactly alike.
Hence, if I have two molecules of methane having exactly the same atoms of carbon and hydrogen,the both are indistinguishable from each other based on appearance.
Hence all molecules of methane are exactly alike if they are composed of atoms of the same isotope of hydrogen and carbon.
What kind of reaction does this make?2 C₅H₅ + Fe ⟶ Fe(C₅H₅)₂A. Synthesis (S)B. Decompostion (D)C. Single Displacement (SD)D. Double Displacement (DD)E. Combustion (C)
The answer is option
The reaction:
\(2C_{5_{}}H_5+Fe\rightarrow Fe(C_5H_5)_2\)is a Synthesis reaction, because from 2 different substances it is produced
Is a red color a physical or chemical property
It is a physical property
Color odour and taste are a properties that are detected by sense organs.
Why are many drugs administered as salts rather than as the corresponding neutral compounds?
A. Salts have greater water solubility and stability than the neutral compound.
B. As a general rule, salts are more active than the neutral compounds.
C. Salts are generally liquid and therefore more active than the neutral compounds.
D. The salts are less expensive to produce than the corresponding neutral compounds.
When a drug is administered as a salt, it is typically combined with an appropriate counterion to form a salt form of the drug. This salt form enhances the solubility of the drug in aqueous solutions, which can improve its bioavailability and allow for better dissolution and absorption in the body.
The correct answer is Many drugs are administered as salts rather than as the corresponding neutral compounds because salts often have greater water solubility and stability. This is important for effective delivery and absorption of the drug in the body. Furthermore, salts often provide improved stability compared to the corresponding neutral compounds. The addition of counterions in the salt form can enhance the chemical and physical stability of the drug molecule, protecting it from degradation or hydrolysis.
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what will be the result of the reaction
(CH3COO)2+redP +Cl2
Answer:
(CH3COO)2 + redP + Cl2 → ClCH2COOH + HCl
Explanation:
This is an example of halogenation of carboxylic acids at alpha carbon atom. In this reaction, red phosphorus and chlorine are treated with carboxylic acids having alpha hydrogen atom followed by hydrolysis to form alpha chloro carboxylic acid.
What is theoretical yield in moles of oxygen when there are 18.3 moles of hydrogen ?
2H2 + O2 --> 2H2O
The theoretical yield of the water in the reaction is 329.4 g.
What is the theoretical yield?
We know that we can be able to obtain the theoretical yield when we look at the stoichiometry of the reaction that we have here. In this case, it is clear that would need to rely on the reaction equation and it would be our guide.
We have that;
2 moles of hydrogen would produce 2 moles of water
18.3 moles of hydrogen would also produce 18.2 moles of water.
Theoretical yield of water would now be;
18.3 * 18 g/mol
= 329.4 g
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a 70.0-g piece of metal at 80.0 oc is placed in 100 g of water at 22.0 oc contained in a calorimeter. the metal and water come to the same temperture at 24.6 oc. how much heat in joules did the metal give up to the water?
A 70.0‑g piece of metal at 80.0 °C is placed in 100 g of water at 22.0 °C contained in a calorimeter. After reaching a temperature of 24.6 °C, the heat given up by the metal to the water is -1.08 kJ.
What is a calorimeter?
A calorimeter is an object used for calorimetry, or the process of measuring the heat of chemical reactions or physical changes as well as heat capacity.
A 70.0‑g piece of metal at 80.0 °C is placed in 100 g of water at 22.0 °C contained in a calorimeter. The final temperature of the system is 24.6 °C.
Let's use the following expression to calculate the heat absorbed by the water.
Qw = c × m × ΔT
Qw = (4.184 J/g.°C) × 100 g × (24.6 °C - 22.0 °C) = 1.08 kJ
where,
Qw is the heat absorbed by the water.
c is the specific heat capacity of water.
m is the mass of water.
ΔT is the change in the temperature for water.
According to the law of conservation of energy, the sum of the heat absorbed by the water and the heat released by the metal (Qm) is zero.
Qw + Qm = 0
Qm = -Qw = -10.8 kJ
A 70.0‑g piece of metal at 80.0 °C is placed in 100 g of water at 22.0 °C contained in a calorimeter. After reaching a temperature of 24.6 °C, the heat given up by the metal to the water is -1.08 kJ.
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Classify NH3 as a strongbase or a weak base.Strong BaseWeak Base
ANSWER
EXPLANATION
Ammonia (NH3) is a base that does not contain hydroxyl ion but dissolved in water to produce ammonium ion and hydroxyl ion.
Recall, that pH scale is one of the tool used in determining a strong base and a weak base
The pH of ammonia is 11 and this make ammonia (NH3) to fall under the category of weak base
Therefore, ammonia is a weak base
The most abundant molecule found in the human body is 88.810% oxygen and
11.190% hydrogen. Calculate the empirical formula for this substance.
The empirical formula for the substance, given the data from the question is H₂O
Data obtained from the questionFrom the question given above, the following data were obtained:
Hydrogen (H) = 11.190%Oxygen (O) = 88.810%Empirical formula =?How to determine the empirical formulaWe can determine the empirical formula for the substance as shown below:
Divide by their molar mass
H = 11.190 / 1 = 11.190
O = 88.810 / 16 = 5.551
Divide by the smallest
H = 11.190 / 5.551 = 2
O = 5.551 / 5.551 = 1
Thus, the empirical formula for the substance that is most abundant in the human body is H₂O
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A liquid is in equilibrium with its vapor in a closed vessel at a fixed temperature. The vessel is connected by a stopcock to an evacuated vessel. When the stopcock is opened, will the final pressure of the vapor be different from the initial value if (a) some liquid remains;
Since there are the same number of molecules in the liquid and vapour phases in this situation, the end pressure would be the same as the initial pressure at equilibrium, before the stopcock was opened.
What is equilibrium, exactly ?When a reversible chemical reaction is occurring, chemical equilibrium is the state in which there is no net change in the number of reactants or products. In a reversible chemical reaction, the products start interacting with the initial reactants as soon as they are created.
We might be able to pinpoint the equilibrium's location using the equilibrium constant. The closer the equilibrium is to the products, the higher the equilibrium constant.Learn more about Equilibrium here:
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Which of the following elements could be prepared by electrolysis of the aqueous solution shown?
Multiple Choice
Sodium from Na3PO4(aq)
Sulfur from K2S04(ed)
Oxygen from H2SO4(aq)
Potassium from KCl(aq)
Nitrogen from AgNO3(aq)
Sodium from Na3PO4(aq) could be prepared by electrolysis of the aqueous solution shown. Based on the provided options, the element that could be prepared by electrolysis of the aqueous solution shown
Potassium from KCl(aq)
Here's why:
- Sodium from Na3PO4(aq) and Nitrogen from AgNO3(aq) are not possible because these ions are more stable in solution than undergoing electrolysis.
- Sulfur from K2S04(ed) is not valid as the compound should be K2SO4(aq) and even then, it would produce oxygen at the anode instead of sulfur.
- Oxygen from H2SO4(aq) can be prepared through electrolysis, but this is not an element directly obtained from the compound.
Potassium from KCl(aq) can be prepared by electrolysis. During this process, K+ ions are reduced to potassium metal at the cathode, and Cl- ions are oxidized to chlorine gas at the anode.
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lithium one of the major chemical building blocks of modern life
True or False
The given statement is "lithium one of the major chemical building blocks of modern life" is false. Lithium is not the budling block of the modern life.
The Lithium is not one of the major chemical the budling block of the modern life. The building blocks of the modern life is the carbon , oxygen, and the nitrogen. There are the six main elements that are the fundamental unit of the building blocks of the life. The order of the buildings blocks of the modern life from the least common to the most common is as follows :
The sulfur, the phosphorous, the oxygen, the nitrogen, the carbon, and the hydrogen.
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A 0.325g of potassium hydrogen phthalate (khp) required 20.15ml of naoh for neutralization. calculate the molarity of naoh.
The molarity of NaOH is calculated to be 0.079 mol/L. It is important to include the correct unit of molarity,
The given information states that the mass of KHP is 0.325 g and the volume of NaOH used is 20.15 mL. To find the molarity of NaOH, we can use the formula: Molarity = number of moles of NaOH / Volume of NaOH in liters. The number of moles of NaOH can be determined by the number of moles of KHP used in the neutralization reaction, as per the balanced chemical equation: KHP + NaOH → NaKP + H2O. In this equation, 1 mole of KHP requires 1 mole of NaOH for neutralization.
To calculate the number of moles of KHP, we divide the mass of KHP by its molar mass. The molar mass of KHP (C8H5KO4) is 204.22 g/mol. Therefore, the number of moles of KHP is 0.325 g / 204.22 g/mol = 0.001591 mol.
Since the stoichiometry of the reaction indicates that the number of moles of NaOH is the same as the number of moles of KHP, the number of moles of NaOH is also 0.001591 mol.
The volume of NaOH used is given as 20.15 mL, which needs to be converted to liters by dividing by 1000. So, the volume of NaOH is 20.15 mL / 1000 = 0.02015 L.
Substituting these values into the formula for molarity, we get Molarity = 0.001591 mol / 0.02015 L = 0.079 mol/L.
Therefore, the molarity of NaOH is calculated to be 0.079 mol/L. It is important to include the correct unit of molarity, which is mol/L or M, in the answer.
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which ion is responsible for the solution being acidic or basic nac2h3o2
The ion responsible for the solution being basic or acidic in NaC2H3O2 is the Acetate ion.
The Acetate ion, CH3COO- is responsible for the solution being acidic or basic in NaC2H3O2.
NaC2H3O2 is also known as Sodium Acetate. It is a common compound in the laboratory that is colorless, deliquescent, and odorless. It dissolves easily in water, and its pH varies depending on the solution's acetate and acetic acid concentration.
Because acetate ion is a weak base, its solution has a higher pH than a solution containing just the acid. The buffer capacity of a solution of the salt NaC2H3O2 (Acetate ion) is dependent on the concentration of the salt and the pH of the solution. A solution with a pH of 7.0 and a 0.1 M NaC2H3O2 concentration would have a buffer capacity of 1.4. A solution with a pH of 5.0 and the same salt concentration would have a buffer capacity of 13.0.The equation for the dissociation of sodium acetate is given below:
NaC2H3O2 ⇌ Na+ + C2H3O2-
We can say that the solution is basic if the pH is greater than 7, acidic if the pH is less than 7, and neutral if the pH is equal to 7.
Hence, the Acetate ion is responsible for the solution being basic or acidic in NaC2H3O2.
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Define the following terms correctly.
1. Reactants-
2. Products-
3. Anion-
4. Cation-
5. Exothermic Reaction-
6. Endothermic Reaction-
1) The substances present before the reaction has occurred.
2) The substances formed after the reaction has occurred.
3) A negatively charged ion, typically non-metal, that gains electrons to become stable.
4) A positively charged ion, typically metal, that losses electrons to become stable.
5) A chemical reaction in which the reactants absorb heat energy from the surroundings to form products.
6) A chemical reaction in which the reactants release heat energy into the surroundings to form products.
what feature related to the composition of a comopund can be determined solely by percent composisi
The % composition of a substance can be used to calculate empirical formulas. The molar mass of the chemical must also be known in order to determine its molecular formula.
What is empirical formula explain?
A compound's various atoms are arranged in an empirical formula in the simplest whole-number ratio.
The exact amount of various atom types that make up a compound's molecule are displayed in the molecular formula. The empirical formula for acetylene is CH. Example: C2H2 is the empirical formula for acetylene.
An illustration of an empirical formula?
Its chemical name is C6H12O6, and it is a simple sugar. Every mole of carbon and oxygen is accompanied by two moles of hydrogen. Glucose's empirical formula is CH2O.
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Asexual reproduction results in two organisms with
Responses
the same DNA.
different DNA.
different parents.
the same parents.
PLEASE HELP FASTT !!
Asexual reproduction results in two organisms with the same parent and the same DNA.
Asexual reproduction produces offspring which are genetically identical to the parent because the offspring are all clones, that is, identical copies of the original parent.
Asexual reproduction in animals occurs through various process such as fission, fragmentation, budding and parthenogenesis. A single individual can produce offspring asexually and large numbers of offspring can be produced quickly with asexual reproduction.
A new potato growing from an old potato can be an example of asexual reproduction. Variation is not possible or significantly reduced in asexual reproduction. Asexual reproduction results in offspring with the same combination of genetic information as the parents.
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the equation 2 al + __f2 → 2 alf3 is balanced by making the coefficient of flourine (f2)
The equation 2Al + _F₂ → 2AlF₃ is balanced by making the coefficient of fluorine, F₂ three (3)
How do i determine the coefficient of fluorine, F₂?To obtain the coefficient of fluorine, F₂ that will balanced the equation, we must obtain the balance equation.
The equation 2Al + _F₂ → 2AlF₃ can be balanced as illustrated below:
2Al + F₂ → 2AlF₃
There are 2 atoms of F on the left side and 6 atoms on the right side. It can be balanced by writing 3 before F₂ as shown below:
2Al + 3F₂ → 2AlF₃
Now, the equation is balanced.
Thus, we can conclude that the coefficient of fluorine, F₂ that balanced the equation is 3
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A 0.258g sample of a powder containing some ascorbic acid required 14.50 ml of 0.100 m naoh for complete neutralization. calculate the purity of the ascorbic acid.
1. \(\rm \text{{moles of NaOH}} = 1.45 \times 10^{-3} \, \text{{mol}}\)
2. The moles of ascorbic acid reacted is also 1.45 × \(10^{-3\) mol.
3. \(\rm \text{{grams of ascorbic acid}} = 0.255 \, \text{{g}}\)
4. The purity of the ascorbic acid in the powder is approximately 98.8%.
To calculate the purity of the ascorbic acid, we can follow these steps:
1. Calculate the moles of NaOH used in the titration:
The volume of NaOH used is 14.50 mL, and the concentration is 0.100 M.
Using the formula:
\(\[\text{{moles of NaOH}} = \text{{concentration}} \times \text{{volume}}\]\\\\text{{moles of NaOH}} = 0.100 \, \text{{M}} \times 14.50 \times 10^{-3} \, \text{{L}}\]\\\\text{{moles of NaOH}} = 1.45 \times 10^{-3} \, \text{{mol}}\]\)
2. Calculate the moles of ascorbic acid reacted:
From the balanced chemical equation of the neutralization reaction, we know that the ratio of NaOH to ascorbic acid is 1:1. Therefore, the moles of ascorbic acid reacted is also 1.45 × \(10^{-3\) mol.
3. Calculate the grams of ascorbic acid in the sample:
To calculate the mass of ascorbic acid, we need to use the molar mass of ascorbic acid, which is 176.12 g/mol.
\(\[\text{{grams of ascorbic acid}} = \text{{moles of ascorbic acid}} \times \text{{molar mass of ascorbic acid}}\]\\\\text{{grams of ascorbic acid}} = 1.45 \times 10^{-3} \, \text{{mol}} \times 176.12 \, \text{{g/mol}}\]\\\\text{{grams of ascorbic acid}} = 0.255 \, \text{{g}}\]\)
4. Calculate the percent purity of the powder:
The purity is the ratio of the mass of pure ascorbic acid to the total mass of the sample, multiplied by 100%.
\(\[\text{{Percent purity}} = \left(\frac{{\text{{grams of ascorbic acid}}}}{{\text{{mass of the sample}}}}\right) \times 100\%\]\\\\text{{Percent purity}} = \left(\frac{{0.255 \, \text{{g}}}}{{0.258 \, \text{{g}}}}\right) \times 100\%\]\\\\text{{Percent purity}} = 98.8\%\]\)
Therefore, the purity of the ascorbic acid in the powder is approximately 98.8%.
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Your question is incomplete, but most probably your full question was.
A 0.258 g sample of a powder containing some ascorbic acid required 14.50 mL of 0.100 M NaOH for complete neutralization. Calculate the purity of the ascorbic acid.
1. moles of NaOH used in the titration________.
2. moles of ascorbic acid reacted________.
3. grams of ascorbic acid in sample_________.
4. Percent purity of the powder________.
When moving down a Column in the periodic table what stays the same ?
Answer:
Explanation:
When we go down in a column , we are going down in a period . In going down , one additional orbit go on adding to the atom . But the total number of electrons in the outermost orbit which is also called valence electron remains the same .
For example , when we go down in the first group A , the outermost orbit go on changing like 1 s¹ , 2 s¹ , 3 s¹ . 4 s ¹ etc which represents hydrogen , lithium . sodium , potassium etc.
So we see that , it is number of valance electrons that remains constant.
During a chemical reaction ____ is never created or destroyed
Answer:
Matter
Explanation:
The Law of Conservation of Mass
What is a characteristic of a Bronsted Lowry acid?
a) ionizes into OH- ions
b) hydrogen ion acceptor
c) hydrogen ion donor
d) electron pair acceptor
Answer:
C. Hydrogen ion donor.
Explanation:
According to bronsted -lowery an acid is a substance that donates a proton (H+) to other substances.
if a person’s stroke volume was 70ml, and the end diastolic volume is increased from 135ml to 165ml, without any changes in arterial pressure. what is the stroke volume in the next few cardiac cycles?
The stroke volume in the next few cardiac cycles will be 100 ml if the end-diastolic volume is increased from 135ml to 165m.
The formula for stroke volume is given as;
SV = EDV - ESV
Here SV represents stroke volume, EDV represents end-diastolic volume and ESV represents end-systolic volume.
First, we calculate this person's end-systolic volume as follows;
If the person’s stroke volume was 70ml and his initial diastolic volume was 135 ml, then:
70 = 135 - ESV
70 - 135 = -ESV
-65 = -ESV
ESV = 65ml
Now the stroke volume in the next few cycles if the end-diastolic volume increase to 165 ml can be calculated as follows;
SV = 165 - 65
SV = 100ml
Therefore, the stroke volume in the next few cardiac cycles is calculated to be 100ml.
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An ideal gas (which is is a hypothetical gas that conforms to the laws governing gas behavior) confined to a container with a massless piston at the top. (Figure 2) A massless wire is attached to the piston. When an external pressure of 2.00 atm is applied to the wire, the gas compresses from 6.40 to 3.20 L . When the external pressure is increased to 2.50 atm , the gas further compresses from 3.20 to 2.56 L .
In a separate experiment with the same initial conditions, a pressure of 2.50 atm was applied to the ideal gas, decreasing its volume from 6.40 to 2.56 L in one step.
If the final temperature was the same for both processes, what is the difference between q for the two-step process and q for the one-step process in joules?
Answer: -162,120J
Explanation:
Okay, so q stands for work, given by the formula q = -P∆V,
For the first round, we have 2atm (for P) and a volume change of 3.2 (6.4-3.2) for the first experiment.
Find the work: q = -2 • (3.2 - 6.4) = 6.4L/atm
For the second experiment, it is now 2.5atm, with the change in volume going from 3.2 to 2.56.
So, work is q = -2.5(2.5 - 3.20) = 1.6L/atm
Add the total work: 1.6 + 6.4 = 8L/atm
To find the Joules per L/atm, recall that a mol of gas in K is 8.31447J, while the gas constant where a liter of gas per mol in K is 0.08206L/atmK. Divide these two values, which leaves us with 101,325J
So, for the first round, multiply 8 x 101,325, which leaves us with 810,600J.
Second round: The pressure is 2.5atm, with the volume change from 6.40 to 2.56
Solve for work: q = -2.5(2.56-6.4) = 9.6L/atm
Multiply with the Joule unit found earlier: 9.6 x 101,325 = 972,720J.
To find the difference, subtract the value of the single-step process (second round) from the first round (multistep)
810600 - 972720 = -162,120J. Therefore, it takes more heat to do the single step than the multistep process.
400 mL of gas is contained at 300 mmHg and 0 °C. What will its volume be at 140 mmHg and 100 °C? 0°C 100°C
Answer:
1171.12 mL
Explanation:
Using the combined gas law equation;
P1V1/T1 = P2V2/T2
Where;
P1 = initial pressure (mmHg)
P2 = final pressure (mmHg)
V1 = initial volume (milliliters)
V2 = final volume (milliliters)
T1 = initial temperature (Kelvin)
T2 = final temperature (Kelvin)
According to the information provided in this question:
P1 = 300 mmHg
P2 = 140 mmHg
V1 = 400 mL
V2 = ?
T1 = 0°C = 273K
T2 = 100°C = 100 + 273 = 373K
Using P1V1/T1 = P2V2/T2
300 × 400/273 = 140 × V2/373
120000/273 = 140V2/373
120000 × 373 = 273 × 140V2
44760000 = 38220V2
V2 = 44760000 ÷ 38220
V2 = 1171.115
The new volume is 1171.12 mL
Which compound is NOT a component of the citric acid cycle? A. Pyruvate B. α-Ketoglutarate C. Succinate D. Malate.
A) Out of the given options, Pyruvate is the compound that is not a component of the citric acid cycle.
The citric acid cycle, also known as the Krebs cycle or the tricarboxylic acid (TCA) cycle, is a central metabolic pathway that occurs in the mitochondria of cells. It is responsible for the oxidation of acetyl-CoA derived from various fuel sources, generating energy in the form of ATP and producing NADH and FADH2.
Pyruvate, which is a product of glycolysis, serves as the starting point for the citric acid cycle. It enters the cycle by being converted into acetyl-CoA through a series of enzymatic reactions.
On the other hand, the compounds α-Ketoglutarate, Succinate, and Malate are all intermediates of the citric acid cycle. They are involved in various steps of the cycle, participating in the generation and transfer of energy-rich electrons and the production of ATP and reduced coenzymes.
Therefore, out of the given options, Pyruvate is the compound that is not a component of the citric acid cycle.
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