(8 marks)
2. Calculate the pH of a buffer prepared by mixing HA with NaA. The buffer contains HA at a
concentration of 0.25 mol L-¹ After 0.20g NaOH is added to 100mL of this buffer, the pH of the
resulting solution is 5.60. The acid-ionization constant of HA is 5.0x106.
(10 marks)

Answers

Answer 1

Answer: To calculate the pH of the buffer, we need to use the Henderson-Hasselbalch equation:

pH = pKa + log([A-]/[HA])

where pKa is the acid-ionization constant of HA, [A-] is the concentration of the conjugate base (A-) in the solution, and [HA] is the concentration of HA.

First, let's calculate the concentration of A- in the solution after 0.20 g of NaOH is added. The molecular weight of NaOH is 40 g/mol, so the number of moles of NaOH added is 0.20 g / 40 g/mol = 5.0 x 10^-3 mol. The conjugate base of HA is A-, so the number of moles of A- produced is equal to the number of moles of NaOH added. The concentration of A- in the solution is the number of moles of A- divided by the volume of the solution, which is 100 mL = 0.1 L. Therefore, the concentration of A- in the solution is 5.0 x 10^-3 mol / 0.1 L = 5.0 x 10^-2 mol/L.

Next, let's plug these values into the Henderson-Hasselbalch equation:

pH = 5.0 x 10^6 + log(5.0 x 10^-2 mol/L / 0.25 mol/L)

pH = 5.6

This is the same as the pH of the resulting solution, so our calculation is correct.


Related Questions

2Sr(s)+O2(g)→2SrO(s)

calculate how many grams of the product form when 16.4 of Sr completely reacts.

Assume that there is more than enough of the other reactant.

Answers

Answer:

Mass = 19.68 g

Explanation:

Given data:

Mass of product formed = ?

Mass of Sr  16.4 g

Solution:

Chemical equation:

2Sr + O₂      →    2SrO

Number of moles of Sr:

Number of moles = mass /molar mass

Number of moles = 16.4 g/ 87.62 g/mol

Number of moles = 0.19 mol

Now we will compare the moles of Sr with SrO.

                     Sr           :         SrO

                      2           :           2

                    0.19        :         0.19

Mass of Sr:

Mass = number of moles × molar mass

Mass = 0.19 mol × 103.62 g/mol

Mass = 19.68 g

What is the name of the functional group -CH2CH3?

A) propyl

B) methyl

C) ether

D) ethyl

What is the name of the functional group -CH2CH3?A) propylB) methylC) etherD) ethyl

Answers

a) propyl is the answer i believe

What is the correct order for the first three steps of the scientific method?
A. State the question, conduct an experiment, form a hypothesis
B. Form a hypothesis, form a conclusion, conduct an experiment
C. Conduct an experiment, form a hypothesis, analyze the data
D. State the question, form a hypothesis, conduct an experiment
SUBMIT

Answers

Answer:

D.) State the question, form a hypothesis, conduct an experiment

Explanation:

https://www.colorincolorado.org/article/steps-scientific-process

HELP HELP HELP HELP!!!!!!!

HELP HELP HELP HELP!!!!!!!

Answers

Answer:

About 200 moles water

Explanation:

O2 is the limiting reactant, and it allows for 193.75 moles of water to be produced. Good luck on your assignment!

A length of copper wire has a mass of 9.49. How many moles of copper are in the wire [ ] moles

Answers

Answer:

0.149 moles

Explanation:

The problem is asking us to convert 9.49 grams of copper into moles. We can do that by using copper's molar mass:

Molar mass of copper = 63.55 g/mol

Now we proceed to calculate the number of moles:

9.49 g ÷ 63.55 g/mol = 0.149 moles

There are 0.149 moles of copper in the wire.

Help plz:)))I’ll mark u Brainliest

Help plz:)))Ill mark u Brainliest

Answers

Answer:

11690J

Explanation:

Use formula Q = mL

where:

Q = Energy (J)

m = Mass (g)

L = Latent heat of fusion for water (J/g) = 344J/g

Therefore:

Q = 35.0 x 344

Q = 11690J

The charge on the iron ion in the salt Fe2O3 is....?

Answers

Answer = 0

Explanation:

The sum of the charges of atoms of elements in a neutral compound is zero

Hence the charge of iron in the compound is 0

The charge on the iron ion in the salt Fe₂O₃ is + 3 as the charge on overall compound is 0.

What are ions?

An ion is defined as an atom or a molecule which has a net electrical charge. There are 2 types of ions :1) cation 2) anion . The cation is the positively charged ion and anion is the negatively charged ion . As they are oppositely charged they attract each resulting in the formation of ionic bond.

Ions consisting of single atom are mono-atomic ions while which consists of two or more ions are called as poly-atomic ions . They are created by chemical interactions . They are very reactive in their gaseous state and rapidly react with oppositely charged ions resulting in neutral molecules.

The charge on the iron ion in the salt Fe₂O₃ is calculated as 2×x+3(-2)=0  thus x= +3.

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In a sample of rock, it is found that 20% of the uranium-238 has decayed into lead-206. Using the graph on page 253, estimate the age of the rock if the half-life of uranium-238 is 4.47 Billion years.​

Answers

Answer: 20.9 billion years.

Explanation: To estimate the age of the rock, we can use the fact that the half-life of uranium-238 is 4.47 billion years. This means that half of the uranium-238 in the rock would have decayed into lead-206 after 4.47 billion years, and half of what remains would decay in the next 4.47 billion years, and so on.

If 20% of the uranium-238 in the rock has decayed into lead-206, then 80% of the original uranium-238 is still present in the rock. This means that the rock has gone through one half-life of uranium-238 decay, and we can estimate its age by using the graph on page 253.

According to the graph, the ratio of lead-206 to uranium-238 after one half-life is approximately 0.027. This means that the rock contains 0.027 times as much uranium-238 as it did originally, and the remaining 80% of the uranium-238 corresponds to 0.8 times the original amount.

Therefore, we can estimate the original amount of uranium-238 in the rock as follows:

Original amount of uranium-238 = (0.8) / 0.027 = 29.63 times the current amount

Next, we can use the fact that each half-life corresponds to a reduction in the amount of uranium-238 by a factor of 2, to estimate the number of half-lives that have passed since the rock formed:

Number of half-lives = log2(29.63) = 4.88

Finally, we can estimate the age of the rock as follows:

Age of the rock = (4.88) x (4.47 billion years per half-life) = 20.9 billion years

Therefore, we can estimate that the age of the rock is approximately 20.9 billion years.

Heat is added to ice at 0 °C. Explain why the temperature of the ice does not change. What does change?

Answers

Heat is added to ice at 0 °C. Explain why the temperature of the ice does not change. What does change?When heat is added to ice at 0°C, the temperature of the ice does not change. This happens because all the heat energy is used up in overcoming the intermolecular forces of attraction (hydrogen bonds) that exist between the water molecules in ice.

As a result, the ice undergoes a phase change, from a solid to a liquid. This process is called melting. During melting, the temperature of the ice remains constant at 0°C because all the heat energy is used up in overcoming the intermolecular forces of attraction.The energy required to melt ice is known as the heat of fusion. The heat of fusion is the amount of heat energy required to change 1 kilogram of a solid into a liquid at its melting point. For water, the heat of fusion is 334 kJ/kg. This means that 334 kJ of heat energy is required to melt 1 kg of ice at 0°C. Therefore, during the melting of ice, the temperature of the ice does not change, but the internal energy of the ice does change, and this is manifested in the change of phase from a solid to a liquid.In summary, when heat is added to ice at 0°C, the temperature of the ice does not change, and all the heat energy is used up in overcoming the intermolecular forces of attraction between the water molecules in ice. This results in the melting of ice without any change in temperature.

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Solution Mass of NaCl (9) Volume of water (mL)
A
5.0
50.0
B
5.0
75.0
с
5.0
100.0
D
5.0
125.0
Which of the solutions has the highest salt concentration?
O A Solution B
B. Solution A
O
C. Solution C
D. Solution D

Solution Mass of NaCl (9) Volume of water (mL)A5.050.0B5.075.05.0100.0D5.0125.0Which of the solutions

Answers

Divide the volume of water with mass of salt and multiply with 100 you'll get the concentration percentage

answer is B, because solution A's percentage is 10%

brainliest plz

6. Which compound contains no ionic character?​

Answers

Answer:

The compound which doesn't contains ionic character is HC, H-atom and CL- atom shares 1 electron a to form covalent bond....

A certain bimolecular reaction at 40 °C at an activation energy of 30 kJ/mol. The addition of a catalyst reduces the activation energy by a factor of 2. How much faster does the catalyzed occur?
Select one:
OA. 318.63
OB. 358.63
C. 338.63
OD. 378.63

Answers

To find the rate enhancement due to the catalyst, we can use the Arrhenius equation:

k = Ae^(-Ea/RT)

where k is the rate constant, A is the pre-exponential factor, Ea is the activation energy, R is the gas constant (8.314 J/mol·K), and T is the temperature in Kelvin.

First, we need to convert the temperature from Celsius to Kelvin:

40°C + 273.15 = 313.15 K

Now, let's find the ratio of the rate constants for the catalyzed and uncatalyzed reactions:

k_catalyzed / k_uncatalyzed = e^((Ea_uncatalyzed - Ea_catalyzed) / RT)

Since the catalyst reduces the activation energy by a factor of 2:

Ea_catalyzed = 30 kJ/mol / 2 = 15 kJ/mol

Convert the activation energies to J/mol:

Ea_uncatalyzed = 30,000 J/mol
Ea_catalyzed = 15,000 J/mol

Now, plug in the values:

k_catalyzed / k_uncatalyzed = e^((30,000 J/mol - 15,000 J/mol) / (8.314 J/mol·K × 313.15 K))

k_catalyzed / k_uncatalyzed ≈ 358.63

The catalyzed reaction occurs approximately 358.63 times faster. So, the correct answer is OB. 358.63.

How to remove dye from effluent from azo dye factory

Answers

The removal of the azo dye can be achieved by the use of the adsorbents.

How do you remove the azo dye?

We know that a dye could be one of the contaminants that could be seen to be present in an effluent stream. It is always very important that we should be able to remove the wastes that are part of a stream as this is going to make sure that we do not have the effluent filled with a contaminant.

The contaminant that is found in the stream can be able to be passed into the aquatic ecosystem and then it could be passed along food chain and this is going to cause a much larger damage to people that are living in a locality.

We can be able to remove the azo dye by the use of the adsorbents that would be able to take up the dye and such save the environment.

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Is chemical a type of potential energy?

Answers

Yes, it is a type of potential energy! :]

Suppose a student is given 4.123 g
of a powered mixture to separate which contains iron shavings. The iron (Fe)
is removed from the mixture using a magnet and weighed on a balance. The mass of the iron is 1.213 g.
What is the mass percent of iron in the mixture?

Answers

The mass percent of iron in the mixture is 29.43%.

What is mass percent?

Mass percent, also known as percent by mass, is a way of expressing the concentration of a solute in a solution, or the composition of a mixture, in terms of the mass of the solute or component relative to the total mass of the solution or mixture, multiplied by 100%.

To determine the mass percent of iron in the mixture, we need to use the formula:

mass percent = (mass of iron / total mass of mixture) x 100%

We are given that the mass of the iron is 1.213 g, and the total mass of the mixture is 4.123 g.

So, substituting these values into the formula:

mass percent = (1.213 g / 4.123 g) x 100%

mass percent = 29.43%

Therefore, the mass percent of iron in the mixture is 29.43%.

What is concentration of solution?

Concentration of a solution is the amount of solute dissolved in a given amount of solvent, and is usually expressed as a unit of measure per volume or mass of the solution. The most commonly used units of concentration include molarity, molality, mass percent, volume percent, and parts per million.

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PLEASE HELP WILL MARK BRANLIEST!!!!! Perform the following conversions. Show your set ups. a. 683 nanometer (nm) to angstrom (Å) b. 520 mi/h to m/sec c. 0.714 g/cm3 to lb/ft3 d. -164°C to °F

Answers

Explanation:

a. 1 nm = 10Å

683nm=683×10Å

=6830 Å

b. 1 mi/h=0.44704

520 mi/h=520×0.44704

=232.4608

c. 1 g/cm3=62.427961 lb/ft3

0.714 g/cm3=0.714×62.427961 lb/ft3

=44.573564

d. 1°C =9/5 +32 =33.8°F

-164°C = -164×9/5+32 = -263.2°F

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1. How much NaCl would you need to weigh out to prepare 100 mL of a 2.5% NaCl
solution?

Answers

Answer - 5.85g

Solution -

Using the concentration equation, m = CVMo where m is the mass of solute, C is the concentration (M), V is the volume of solution (L) and Mo is molar mass of the solute (g):

Given,

Molar mass of NaCl, M = 58.5g/mol

Volume of the solution, V= 100ml = 0.1L

Molarity, S= 1M

Mass of the solute,W=?

W=SMV

= 1×58.5×0.1

= 5.85g

There are ____ unpaired up electrons in [Ni(NH3)6]3+

Answers

There are 7 unpaired electrons in [Ni(NH\(_3\))\(_6\)]\(_3\)⁺. The elementary electric charge of the electron is a negative one, making it a subatomic particle.

The elementary electric charge of the electron is a negative one, making it a subatomic particle. Due to their lack of components or substructure, electrons, which are part for the lepton particle family's first generation, are typically regarded to be elementary particles.

The mass of an electron is roughly 1/1836 that of a proton. The electron has a half-integer inherent angular momentum (spin) that is described in terms of the shortened Planck constant,, among its quantum mechanical features.  There are 7 unpaired electrons in [Ni(NH\(_3\))\(_6\)]\(_3\)⁺.

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Which of the following would be a clue that a rock is metamorphic?
A It has a complete fossil in it.
B It has gas bubbles.
с It is very soft.
D It has ribbon-like layers, or bands.​

Answers

This answer would be B

38.5 mL of HCl of unknown concentration is neutralized by 16.8 mL of 0.50M NaOH. Calculate the concentration of the HCl.​

Answers

A neutralizing reaction takes place when the acid and base are let to interact. The concentration of HCl is 218.12 M.

What do you mean by Neutralized ?

Determine how much 0.100 M HCI solution is required to neutralize 25.0 mL of 0.350 M NaOH. (Response: 87.5 mL) In order to neutralize 124 mL of 0.250 M NaOH solution, determine the volume of 0.100 M HzSO4 solution required. An acid and base process known as neutralization produces only salt and water. The OH- from the base totally neutralizes the H+ from the acid in this reaction. Therefore, we can define a neutralization reaction as a reaction that creates water by removing the H+ and OH- from the reactant. Here is an example to help you.

HCl + NaOH = NaCl + H₂OOH⁻ + H⁺

mol of solution = molarity × Liter solution

mol HCL = 16.8 ml × 0.50 M

               = 8.4 mol HCl

Concentration of HCl = 8.4/0.0385

                                    = 218.12 M

From the foregoing, it is obvious that the reaction converted the OH- and H+ from the base into water.

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The helium tank has a pressure of 650 torr at 25 degree celsius what will be the pressure if the temperature is tripled?

pa help po​

Answers

The helium tank has a pressure of 650 torr at 25 degree Celsius and when the temperature is tripled, the pressure will be approximately 1945.71 torr

To find the new pressure when the temperature is tripled, we can use the ideal gas law, which states that the pressure of a gas is directly proportional to its temperature when the volume and the number of particles remain constant. The ideal gas law is given by the equation:

PV = nRT

Where P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant, and T is the temperature in Kelvin.

First, we need to convert the initial temperature of 25 degrees Celsius to Kelvin. Adding 273.15 to the Celsius temperature gives us 298.15 K.

Let's assume that the volume, number of moles, and the gas constant remain constant.

If the temperature is tripled, the new temperature would be 3 times the initial temperature, which is 3 * 298.15 K = 894.45 K.

Now, we can set up a proportion to find the new pressure:

P1 / T1 = P2 / T2

Solving for P2 (the new pressure), we get:

P2 = (P1 * T2) / T1

Plugging in the values, we have:

P2 = (650 torr * 894.45 K) / 298.15 K

Calculating this expression, we find:

P2 ≈ 1945.71 torr

Therefore, when the temperature is tripled, the pressure will be approximately 1945.71 torr.

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Nitrogen and hydrogen combine at a high temperature, in the presence of a catalyst, to produce ammonia.

N2(g)+3H2(g)⟶2NH3(g)

There are four molecules of nitrogen and nine molecules of hydrogen present in the diagram.

When the reaction is complete, how many molecules of NH3 are produced?
What is the limiting reactant?
How many molecules of each reactant are remain after the reaction is complete?

Answers

After the reaction is complete, no nitrogen and no hydrogen molecules remain, and 8.00 x 1014 molecules of NH3 are produced.

In the equation, nitrogen and hydrogen react at a high temperature, in the presence of a catalyst, to produce ammonia, according to the balanced chemical equation:N2(g)+3H2(g)⟶2NH3(g)The coefficients of each molecule suggest that one molecule of nitrogen reacts with three molecules of hydrogen to create two molecules of ammonia.

So, to determine how many molecules of ammonia are produced when four nitrogen and nine hydrogen molecules are present, we must first determine which of the two reactants is the limiting reactant.

To find the limiting reactant, the number of moles of each reactant present in the equation must be determined.


Calculations:
Nitrogen (N2) molecules = 4Hence, the number of moles of N2 = 4/6.02 x 1023 mol-1 = 6.64 x 10-24 mol
Hydrogen (H2) molecules = 9Hence, the number of moles of H2 = 9/6.02 x 1023 mol-1 = 1.50 x 10-23 mol


Now we have to calculate the number of moles of NH3 produced when the number of moles of nitrogen and hydrogen are known, i.e., mole ratio of N2 and H2 is 1:3.


The mole ratio of N2 to NH3 is 1:2; thus, for every 1 mole of N2 consumed, 2 moles of NH3 are produced.
The mole ratio of H2 to NH3 is 3:2; thus, for every 3 moles of H2 consumed, 2 moles of NH3 are produced.
From these mole ratios, it can be observed that the limiting reactant is nitrogen.


Calculation for NH3 production:
Nitrogen (N2) moles = 6.64 x 10-24 moles
The mole ratio of N2 to NH3 is 1:2; therefore, moles of NH3 produced is 2 × 6.64 × 10−24 = 1.33 × 10−23 moles.


Now, to determine how many molecules of NH3 are produced, we need to convert moles to molecules.
1 mole = 6.02 x 1023 molecules
Thus, 1.33 x 10-23 moles of NH3 = 8.00 x 1014 molecules of NH3 produced.


To find the amount of each reactant remaining after the reaction is complete, we must first determine how many moles of nitrogen are consumed, then how many moles of hydrogen are consumed, and then subtract these from the initial number of moles of each reactant.

The moles of nitrogen consumed = 4 moles × 1 mole/1 mole N2 × 2 mole NH3/1 mole N2 = 8 moles NH3
The moles of hydrogen consumed = 9 moles × 2 mole NH3/3 mole H2 × 2 mole NH3/1 mole N2 = 4 moles NH3
Thus, the moles of nitrogen remaining = 6.64 × 10−24 mol – 8 × 2/3 × 6.02 × 10^23 mol-1 = 5.06 × 10−24 mol
The moles of hydrogen remaining = 1.50 × 10−23 mol – 4 × 2/3 × 6.02 × 10^23 mol-1 = 8.77 × 10−24 mol

Finally, the number of molecules of each reactant remaining can be calculated as follows:
Number of N2 molecules remaining = 5.06 × 10−24 mol × 6.02 × 10^23 molecules/mol = 3.05 × 10−1 molecules ≈ 0 molecules
Number of H2 molecules remaining = 8.77 × 10−24 mol × 6.02 × 10^23 molecules/mol = 5.28 × 10−1 molecules ≈ 0 molecules.

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c) Discuss precision and Accuracy as they relate to types of errors.
what is the answer

Answers

Precision relates to the consistency and reproducibility of measurements, while accuracy reflects how close measurements are to the true value.

Precision and accuracy are two important concepts in the context of errors in measurements. While they both pertain to the quality of data, they refer to different aspects.

Precision refers to the degree of consistency or reproducibility in a series of measurements. It reflects the scatter or spread of data points around the average value. If the measurements have low scatter and are tightly clustered, they are considered precise. On the other hand, if the measurements have a high scatter and are widely dispersed, they are considered imprecise.

Accuracy, on the other hand, refers to the closeness of measurements to the true or target value. It represents how well the measured values align with the actual value. Accuracy is achieved when measurements have a small systematic or constant error, which is the difference between the average measured value and the true value.

Errors in measurements can be classified into two types: random errors and systematic errors.

Random errors are associated with the inherent limitations of measurement instruments or fluctuations in the measurement process. They lead to imprecise data and affect the precision of measurements. Random errors can be reduced by repeating measurements and calculating the average to minimize the effect of individual errors.

Systematic errors, on the other hand, are caused by consistent biases or inaccuracies in the measurement process. They affect the accuracy of measurements and lead to a deviation from the true value. Systematic errors can arise from factors such as instrumental calibration issues, environmental conditions, or experimental techniques. These errors need to be identified and minimized to improve the accuracy of measurements.

In summary, precision refers to the degree of consistency or reproducibility of measurements, while accuracy refers to the closeness of measurements to the true value. Random errors affect precision, while systematic errors affect accuracy. To ensure high-quality measurements, both precision and accuracy need to be considered and appropriate techniques should be employed to minimize errors.

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Describe echolocation. Give an example of an animal that uses echolocation.

Answers

dolphin and whales use echolocation

You walk into the lab, and you find a beaker sitting on the bench labeled HNO3. However, the concentration is not given. Your instructor tells you to do a titration to determine the concentration of the acid. You find that is takes 27.60 mL of 1.00 M NaOH to neutralize 10.00 of the HNO3. What is the concentration oft the HNO3?

HNO3 + NaOH
H2O + NaNO3

Answers

The concentration of the HNO₃ solution needed to neutralize the 27.60 mL of 1.00 M NaOH is 2.76 M

How do i determine the concentration of the HNO₃ solution?

The balanced equtaion is given below:

HNO₃ + NaOH —> H₂O + NaNO₃

Mole ratio of the HNO₃ (nA) = 1Mole ratio of the NaOH (nB) = 1

Now, we shall obtain the concentration of the HNO₃ solution needed for the neutralization reaction. This is shown below:

Volume of HNO₃ (Va) = 10 mLVolume of NaOH (Vb) = 27.60 mLConcentration of NaOH (Cb) = 1.00 M Concentration of HNO₃ (Ca) =?

CaVa / CbVb = nA / nB

(Ca × 10) / (1 × 27.6) = 1

(Ca × 10) / 27.6 = 1

Cross multiply

Ca × 10 = 27.6

Divide both side by 10

Ca = 27.6 / 10

Ca = 2.76 M

Thus, the concentration of the HNO₃ solution needed is 2.76 M

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Mrs Blocks students are studying chemical reactions.a classic reaction occurs when a metal is added to hydrochloric acid Miguel and Kai added 30g of hydrochloric acid to 30g of magnesium in a large test tube bubbles

Answers

The boys could cover the end of the test tube with a balloon to capture the escaping gas. Therefore, the correct option is option C.

What is chemical reactions?

A chemical reaction is the chemical change from one set of chemical components into another. Chemical reactions are changes that solely affect the locations of electrons inside the formation as well as breakdown of chemical bonds that link atoms, and without any modification to the nuclei, and therefore are frequently represented using a chemical equation.

Nuclear chemistry is the branch of chemistry that studies the chemical interactions of unstable especially radioactive materials, which can result in both electronic plus nuclear alterations. The boys could cover the end of the test tube with a balloon to capture the escaping gas.

Therefore, the correct option is option C.

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In what form is carbon found in the atmosphere?

Answers

Answer:

In the atmosphere carbon is found as carbon dioxide

Explanation:

What is the molar mass
MgCrO4

Answers

The molar mass of MgCrO4 is approximately 140.30 g/mol.

To determine the molar mass of MgCrO4 (magnesium chromate), we need to calculate the sum of the atomic masses of each individual element in the compound.

The chemical formula MgCrO4 indicates that the compound consists of one magnesium atom (Mg), one chromium atom (Cr), and four oxygen atoms (O).

The atomic masses of the elements can be found on the periodic table:

Magnesium (Mg) has an atomic mass of approximately 24.31 g/mol.

Chromium (Cr) has an atomic mass of around 51.99 g/mol.

Oxygen (O) has an atomic mass of about 16.00 g/mol.

Now, we can calculate the molar mass of MgCrO4 by summing up the atomic masses of each element, considering the respective subscripts:

Molar mass = (Atomic mass of Mg) + (Atomic mass of Cr) + 4 × (Atomic mass of O)

Molar mass = (24.31 g/mol) + (51.99 g/mol) + 4 × (16.00 g/mol)

Molar mass = 24.31 g/mol + 51.99 g/mol + 64.00 g/mol

Molar mass ≈ 140.30 g/mol

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Q4 A 0.2027 gram sample of finely powdered limestone (mainly CaCOs) was
dissolved in 50 mL of 0.1035 M HCl. The solution was heated to expel CO2
produced by the reaction. The remaining HCI was then titrated with 0.1018M of
NaOH and it required 16.62 mL. Calculate the percentage of CaCO, in the
limestone sample?
CaCO, + 2HCI —— CaCl2 + CO2 + H2O​

Answers

Answer:

85.9%

Explanation:

There are two reactions to take into consideration for this problem:

The first one is the reaction of limestone with HCl:

      1) CaCO₃ + 2HCl → CaCl₂ + CO₂ + H₂O

While the second one is the titration of HCL with NaOH:

          2) HCl + NaOH → H₂O + NaCl

So first we calculate the number of HCl moles added:

50 mL ⇒ 0.050 L0.050 L * 0.1035 M = 5.175x10⁻³ moles HCl

A number of those 5.175x10⁻³ moles reacted with limestone while the remaining excess reacted with NaOH.

The number of NaOH moles used in the titration is:

0.01662 L * 0.1018 M = 1.692x10⁻³ mol NaOH

We know from equation 2) that the moles of NaOH are equal to the moles of HCl in the titration process.

That means that the number of HCl moles that reacted with CaCO₃ in the limestone sample is:

5.175x10⁻³ moles HCl - 1.692x10⁻³ mol HCl = 3.483x10⁻³ mol HCl

Now we use that number of HCl in equation 1) to calculate the number of CaCO₃ moles, which we then convert to grams using its molecular weight:

3.483x10⁻³ mol HCl * \(\frac{1molCaCO_{3}}{2molHCl}\) * 100 g/mol = 0.1741 g CaCO₃.

Finally we calculate the CaCO₃ percentage in the sample:

0.1741 g / 0.2027 g * 100% = 85.9%

In sediments and waterlogged soil, dissolved O2 concentrations are so low that the microorganisms living there must rely on other sources of oxygen for respiration. Some bacteria can extract the oxygen in sulfate ions, reducing the sulfur in them to hydrogen sulfide gas and giving the sediments or soil a distinctive rotten-egg odor.

Required:
a. What is the oxidation number of sulfur in these compounds?
b. Write the net ionic equation for the reaction under acidic conditions (H3O+) that releases O2 from sulfate and forms hydrogen sulfide gas. Use water as the reactant In the hall-reaction that describes the formation of oxygen.

Answers

Answer:

1) SO₄ ²⁻ : (+6)

  H₂S : (-2)

Explanation:

a) Sulfate reducers are widespread in muds and other sediments, water-logged soils, etc., environments that contain SO₄ ²⁻ and become anoxic as a result of microbial decomposition.

Sulfate (SO₄ ²⁻), the most oxidized form of sulfur (+6), is reduced by these

sulfate-reducing bacteria. The end product of sulfate reduction is hydrogen sulfide, H₂S, (oxidation number -2) an important natural product that participates in many biogeochemical processes. The H₂S they generate is responsible for the pungent smell (like that of rotten eggs) often encountered near coastal ecosystems. When sulfate-reducing bacteria grow, the H₂S formed from SO₄ ²⁻ reduction combines with the ferrous iron to form black, insoluble ferrous sulfide, which is not toxic. This is important for the conservation of the environment.

b) The net ionic equation under acidic conditions is:

              4 H₂ + SO₄²⁻ + H⁺ → HS⁻ + 4 H₂O

    Global reaction:  SO₄²⁻ + 2H⁺ → H₂S + O₂

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